КФУ. Карточка публикации. Mn-catalyzed oxydation of heavy oil in porous media: kinetics and some aspects of mechanism

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MN-CATALYZED OXYDATION OF HEAVY OIL IN POROUS MEDIA: KINETICS AND SOME ASPECTS OF MECHANISM

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2016

Язык

английский

Авторы, сотрудники КФУ

Биктагиров Тимур Булатович, автор

Галухин Андрей Владимирович, автор

Гафуров Марат Ревгерович, автор

Герасимов Александр Владимирович, автор

Орлинский Сергей Борисович, автор

Родионов Александр Александрович, автор

Библиографическое описание на языке оригинала

A. V. Galukhin, M. A. Khelkhal, A. V. Gerasimov, T. Biktagirov, M. R Gafurov, A. Rodionov, S. B. Orlinskii Mn-catalyzed oxydation of heavy oil in porous media: kinetics and some aspects of mechanism, Energy and Fuels 2016, 30, 7731−7737.

Аннотация

Mn-catalyzed oxidation of the Ashalcha heavy oil in porous media was examined. We used manganese(III) tris(acetylacetonate) as a convinient oil-soluble precatalyst that decomposes to catalytically active species during the temperature ramping. Reaction kinetics in the heavy oil oxidation with air indicated that the presence of the manganese ions changes the mechanism of the oxidation process, especially in the high-temperature region. To study precatalyst transformations in detail, we suggested the approach of combining X-ray powder diffraction (XRPD), thermal analysis, non-isothermal kinetic methods, and electron paramagnetic resonance (EPR). A comprehensive study of the decomposition of pure manganese(III) tris(acetylacetonate) and the subsequent comparison of its behavior to that in porous media in the presence of the oil allows us to shed light on some aspects of the mechanism of catalytic oxidation.

Ключевые слова

Heavy oil, EPR, TG DSC

Название журнала

Energy and Fuels

URL

http://pubs.acs.org/doi/abs/10.1021/acs.energyfuels.6b01234

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https://repository.kpfu.ru/?p_id=139376

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Биктагиров Тимур Булатович	ru_RU
dc.contributor.author	Галухин Андрей Владимирович	ru_RU
dc.contributor.author	Гафуров Марат Ревгерович	ru_RU
dc.contributor.author	Герасимов Александр Владимирович	ru_RU
dc.contributor.author	Орлинский Сергей Борисович	ru_RU
dc.contributor.author	Родионов Александр Александрович	ru_RU
dc.date.accessioned	2016-01-01T00:00:00Z	ru_RU
dc.date.available	2016-01-01T00:00:00Z	ru_RU
dc.date.issued	2016	ru_RU
dc.identifier.citation	A. V. Galukhin, M. A. Khelkhal, A. V. Gerasimov, T. Biktagirov, M. R Gafurov, A. Rodionov, S. B. Orlinskii Mn-catalyzed oxydation of heavy oil in porous media: kinetics and some aspects of mechanism, Energy and Fuels 2016, 30, 7731−7737.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=139376	ru_RU
dc.description.abstract	Energy and Fuels	ru_RU
dc.description.abstract	Mn-catalyzed oxidation of the Ashalcha heavy oil in porous media was examined. We used manganese(III) tris(acetylacetonate) as a convinient oil-soluble precatalyst that decomposes to catalytically active species during the temperature ramping. Reaction kinetics in the heavy oil oxidation with air indicated that the presence of the manganese ions changes the mechanism of the oxidation process, especially in the high-temperature region. To study precatalyst transformations in detail, we suggested the approach of combining X-ray powder diffraction (XRPD), thermal analysis, non-isothermal kinetic methods, and electron paramagnetic resonance (EPR). A comprehensive study of the decomposition of pure manganese(III) tris(acetylacetonate) and the subsequent comparison of its behavior to that in porous media in the presence of the oil allows us to shed light on some aspects of the mechanism of catalytic oxidation.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Heavy oil	ru_RU
dc.subject	EPR	ru_RU
dc.subject	TG DSC	ru_RU
dc.title	Mn-catalyzed oxydation of heavy oil in porous media: kinetics and some aspects of mechanism	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU