КФУ. Карточка публикации. The mechanism of the dielectric relaxation in water

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THE MECHANISM OF THE DIELECTRIC RELAXATION IN WATER

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2016

Язык

английский

Авторы, сотрудники КФУ

Хамзин Айрат Альбертович, автор

Библиографическое описание на языке оригинала

Popov I, Ishai P.B, Khamzin A, The mechanism of the dielectric relaxation in water//Physical Chemistry Chemical Physics. - 2016. - Vol.18, Is.20. - P.13941-13953.

Аннотация

Although relating to the same system, the interpretations of the water spectra from Raman and Dielectric spectroscopy present independent pictures of the nature of water. We show that in the overlap region of the two methods it is possible to combine these views into a coherent concept of what drives the dynamic features of water. In this work, we develop the idea that the dielectric relaxation in water is driven by the migration of defects through the H-bond network, leading to a Debye-like peak in the lower frequencies. The deviation from the Debye law in the higher sub-THz frequencies is traced to a global fluctuation of the same H-bond network, clearly evident in the Raman Spectra. By incorporating these two views, a mathematical formalism is presented that can aptly explicate the dielectric spectra of liquid water.

Ключевые слова

Диэлектрическая релаксация, водородная связь, функция Коула-Коула

Название журнала

Physical Chemistry Chemical Physics

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-84970028346&partnerID=40&md5=bf7e01522e58e7c78087b63732850480

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https://repository.kpfu.ru/?p_id=137956

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Хамзин Айрат Альбертович	ru_RU
dc.date.accessioned	2016-01-01T00:00:00Z	ru_RU
dc.date.available	2016-01-01T00:00:00Z	ru_RU
dc.date.issued	2016	ru_RU
dc.identifier.citation	Popov I, Ishai P.B, Khamzin A, The mechanism of the dielectric relaxation in water//Physical Chemistry Chemical Physics. - 2016. - Vol.18, Is.20. - P.13941-13953.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=137956	ru_RU
dc.description.abstract	Physical Chemistry Chemical Physics	ru_RU
dc.description.abstract	Although relating to the same system, the interpretations of the water spectra from Raman and Dielectric spectroscopy present independent pictures of the nature of water. We show that in the overlap region of the two methods it is possible to combine these views into a coherent concept of what drives the dynamic features of water. In this work, we develop the idea that the dielectric relaxation in water is driven by the migration of defects through the H-bond network, leading to a Debye-like peak in the lower frequencies. The deviation from the Debye law in the higher sub-THz frequencies is traced to a global fluctuation of the same H-bond network, clearly evident in the Raman Spectra. By incorporating these two views, a mathematical formalism is presented that can aptly explicate the dielectric spectra of liquid water.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Диэлектрическая релаксация	ru_RU
dc.subject	водородная связь	ru_RU
dc.subject	функция Коула-Коула	ru_RU
dc.title	The mechanism of the dielectric relaxation in water	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU