КФУ. Карточка публикации. Investigation of Tetramethylenesulfonated Calix[4]Resorcinarene Interactions with Azo-Dyes in Aqueous Solution

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INVESTIGATION OF TETRAMETHYLENESULFONATED CALIX[4]RESORCINARENE INTERACTIONS WITH AZO-DYES IN AQUEOUS SOLUTION

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2010

Язык

английский

Авторы, сотрудники КФУ

Коновалов Александр Иванович, автор

Миронова Диана Александровна, автор

Морозова Юлия Эрнестовна, автор

Шалаева Яна Викторовна, автор

Другие авторы

Казакова Элла Хатибовна, автор

Макарова Нэли Александровна, автор

Сякаев Виктор Васильевич, автор

Библиографическое описание на языке оригинала

Morozova Ju. E. Investigation of Tetramethylenesulfonated Calix[4]Resorcinarene Interactions with Azo-Dyes in Aqueous Solution. / Morozova Ju. E., Kazakova E. Kh., Mironova D. A., Shalaeva Ya. V., Syakaev V. V., Makarova N. A., Konovalov A. I. // J. Phys. Chem. B. - 2010. - V.114, No. 41. - P. 13152–13158.

Аннотация

Here, we report on the interactions of nonaggregated methyl-substituted (SCA1) and aggregated penthyl-substituted (SCA2) tetramethylenesulfonated calix[4]resorcinarenes with pH indicators methyl yellow (MY) and methyl orange (MO) in aqueous solutions. It was found that the pH of aqueous solutions of SCA1 and SCA2 depends on their concentration; besides, variation of the concentration of SCA1 and SCA2 results in a shift of the absorption maxima and of pH-sensitive azo dyes. Association of the marocycles with azo dyes was demonstrated to follow a proton-transfer mechanism accompanied by protonation of the dyes; it was found that excess of the macrocycle in solution with the universal buffer background shifts the pKa values and stabilizes the protonated form of the dyes.

Ключевые слова

Calix[4]resorcinarene, aggregation, pH indicator, pKa value shift

Название журнала

J PHYS CHEM B

URL

http://pubs.acs.org/doi/abs/10.1021/jp106060p

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https://repository.kpfu.ru/?p_id=139093

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Коновалов Александр Иванович	ru_RU
dc.contributor.author	Миронова Диана Александровна	ru_RU
dc.contributor.author	Морозова Юлия Эрнестовна	ru_RU
dc.contributor.author	Шалаева Яна Викторовна	ru_RU
dc.contributor.author	Казакова Элла Хатибовна	ru_RU
dc.contributor.author	Макарова Нэли Александровна	ru_RU
dc.contributor.author	Сякаев Виктор Васильевич	ru_RU
dc.date.accessioned	2010-01-01T00:00:00Z	ru_RU
dc.date.available	2010-01-01T00:00:00Z	ru_RU
dc.date.issued	2010	ru_RU
dc.identifier.citation	Morozova Ju. E. Investigation of Tetramethylenesulfonated Calix[4]Resorcinarene Interactions with Azo-Dyes in Aqueous Solution. / Morozova Ju. E., Kazakova E. Kh., Mironova D. A., Shalaeva Ya. V., Syakaev V. V., Makarova N. A., Konovalov A. I. // J. Phys. Chem. B. - 2010. - V.114, No. 41. - P. 13152–13158.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=139093	ru_RU
dc.description.abstract	J PHYS CHEM B	ru_RU
dc.description.abstract	Here, we report on the interactions of nonaggregated methyl-substituted (SCA1) and aggregated penthyl-substituted (SCA2) tetramethylenesulfonated calix[4]resorcinarenes with pH indicators methyl yellow (MY) and methyl orange (MO) in aqueous solutions. It was found that the pH of aqueous solutions of SCA1 and SCA2 depends on their concentration; besides, variation of the concentration of SCA1 and SCA2 results in a shift of the absorption maxima and of pH-sensitive azo dyes. Association of the marocycles with azo dyes was demonstrated to follow a proton-transfer mechanism accompanied by protonation of the dyes; it was found that excess of the macrocycle in solution with the universal buffer background shifts the pKa values and stabilizes the protonated form of the dyes.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Calix[4]resorcinarene	ru_RU
dc.subject	aggregation	ru_RU
dc.subject	pH indicator	ru_RU
dc.subject	pKa value shift	ru_RU
dc.title	Investigation of Tetramethylenesulfonated Calix[4]Resorcinarene Interactions with Azo-Dyes in Aqueous Solution	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU