Казанский (Приволжский) федеральный университет, КФУ
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GAS/SOLID COMPLEXATION AND INCLUSION
Форма представленияЗарубежные монографии
Год публикации2016
Языканглийский
  • Гатиатулин Аскар Камилевич, автор
  • Горбачук Валерий Виленович, автор
  • Зиганшин Марат Ахмедович, автор
  • Библиографическое описание на языке оригинала V.V. Gorbatchuk Gas/Solid Complexation and Inclusion / V.V. Gorbatchuk, A.K. Gatiatulin, M.A. Ziganshin // Reference Module in Chemistry, Molecular Sciences and Chemical Engineering 2016
    Аннотация Gas/solid complexation and inclusion are a versatile method used for gas and vapor sensing, storage and separation, preparation of inclusion compounds, and the study of structure?property relationships for host?guest crystals. Gas/solid complexation and inclusion may provide a genuine molecular recognition, which is not based on the ordinary lock-and-key concept. In this article, experimental procedures are reviewed, which are used to reach a permanent, virtual, or metastable host porosity, maximal selectivity, or reversibility of guest adsorption/inclusion, to enable inclusion of a target guest overcoming threshold by its thermodynamic activity and to make the host eligible for experimental measurements of thermodynamic inclusion parameters.
    Ключевые слова Adsorption isotherm, Calixarene, Clathrate preparation, Cyclodextrin, Guest exchange, Hydration effect, Inclusion compound, Inclusion Gibbs energy, Inclusion irreversibility, Inclusion threshold, Molecular recognition, Phase transition, QCM sensor, Sorption cooperativity, Structure?property relationship
    URL http://www.sciencedirect.com/science/article/pii/B9780124095472124990
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