Казанский (Приволжский) федеральный университет, КФУ
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DESIGN AND APPLICATIONS OF SUPRAMOLECULAR SYSTEMS BASED ON (THIA)CALIXARENE AMMONIUM DERIVATIVES
Форма представленияЗарубежные монографии
Год публикации2017
Языкрусский
  • Андрейко Елена Анатольевна, автор
  • Падня Павел Леонидович, автор
  • Стойков Иван Иванович, автор
  • Пуплампу Джошуа Буер, автор
  • Библиографическое описание на языке оригинала Stoikov I. I. Design and applications of supramolecular systems based on (thia)calixarene ammonium derivatives, Supramolecular Systems: Chemistry, Types and Applications / (I. I. Stoikov, P. L. Padnya, E. A. Andreyko, J.B. Puplampu. - New York, Nova Publishers, 2017. - 1-38 p.
    Аннотация Currently in supramolecular chemistry, much attention is devoted to scientific fields like molecular recognition, catalysis, self-assembly and nano-medicine which are essential in the development of science and industry. The design of synthetic receptors capable of recognizing different types of guests is a prerequisite in the construction of sensors, catalysts, biomimetic systems, selective extractants, drug delivery systems and programmable materials. The unique properties of (thia)calix[n]arenes (they exist in several configurations, the possibility of functionalizing them with different binding sites and the ability to fix these centers in the required spatial orientation) offer great opportunities in the design of synthetic receptors. The major setback of (thia)calixarene receptors is their poor solubility in water. However, introducing charged groups such as ammonium, phosphate, carboxylate and sulfonate enhances the water solubility of the macrocycles. The ammonium group is one
    Ключевые слова (thia)calixarenes, synthesis, ammonium salt, self-assemly, association
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