Форма представления | Статьи в зарубежных журналах и сборниках |
Год публикации | 2017 |
Язык | английский |
|
Балакин Константин Валерьевич, автор
Булатов Тимур Маратович, автор
Гнездилов Олег Иванович, автор
Иксанова Альфия Габдулахатовна, автор
Исламов Даут Ринатович, автор
Нгуен Тхи Нят Тханг , автор
Павельев Роман Сергеевич, автор
Пугачев Михаил Владимирович, автор
Штырлин Юрий Григорьевич, автор
|
Библиографическое описание на языке оригинала |
Pugachev, M.V. Wittig reactions of a bis-triphenylphosphonium pyridoxine derivative / M.V. Pugachev, T.M. Bulatov, T.T.N. Nguyen, R.S. Pavelyev, O.I. Gnezdilov, O.A. Lodochnikova, D.R. Islamov, O.N. Kataeva, K.V. Balakin, Y.G. Shtyrlin // Tetrahedron Letters – 2017. – V. 58, Iss. 8. – P. 766-769. |
Аннотация |
Wittig reactions of a bis-triphenylphosphonium pyridoxine derivative with five aromatic and aliphatic
aldehydes led to a series of mono- and bis-alkenyl substituted products. The reactions also demonstrated
unusual reactivity patterns leading to unexpected products, including a Z-shaped hyperconjugated structure
with trans-configuration for all three alkene fragments, and a tricyclic 9,10-dihydro-1H-[1,3]dioxino
[4,5-c]quinoline formed as a result of non-symmetric Wittig olefination followed by a rare type of
intramolecular cyclization. The obtained products represent prospective biologically active agents, while
one compound is a potential microenvironment- and interaction-sensitive molecular probe. |
Ключевые слова |
Pyridoxine, wittig reaction, hydrolysis oxidation, intramolecular cyclization |
Название журнала |
Tetrahedron Letters
|
URL |
https://www.scopus.com/inward/record.url?eid=2-s2.0-85009865424&partnerID=40&md5=12e97dc1bbb10e21865fb12b9f907d65 |
Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=163196 |
Файлы ресурса | |
|
Полная запись метаданных |
Поле DC |
Значение |
Язык |
dc.contributor.author |
Балакин Константин Валерьевич |
ru_RU |
dc.contributor.author |
Булатов Тимур Маратович |
ru_RU |
dc.contributor.author |
Гнездилов Олег Иванович |
ru_RU |
dc.contributor.author |
Иксанова Альфия Габдулахатовна |
ru_RU |
dc.contributor.author |
Исламов Даут Ринатович |
ru_RU |
dc.contributor.author |
Нгуен Тхи Нят Тханг |
ru_RU |
dc.contributor.author |
Павельев Роман Сергеевич |
ru_RU |
dc.contributor.author |
Пугачев Михаил Владимирович |
ru_RU |
dc.contributor.author |
Штырлин Юрий Григорьевич |
ru_RU |
dc.date.accessioned |
2017-01-01T00:00:00Z |
ru_RU |
dc.date.available |
2017-01-01T00:00:00Z |
ru_RU |
dc.date.issued |
2017 |
ru_RU |
dc.identifier.citation |
Pugachev, M.V. Wittig reactions of a bis-triphenylphosphonium pyridoxine derivative / M.V. Pugachev, T.M. Bulatov, T.T.N. Nguyen, R.S. Pavelyev, O.I. Gnezdilov, O.A. Lodochnikova, D.R. Islamov, O.N. Kataeva, K.V. Balakin, Y.G. Shtyrlin // Tetrahedron Letters – 2017. – V. 58, Iss. 8. – P. 766-769. |
ru_RU |
dc.identifier.uri |
https://repository.kpfu.ru/?p_id=163196 |
ru_RU |
dc.description.abstract |
Tetrahedron Letters |
ru_RU |
dc.description.abstract |
Wittig reactions of a bis-triphenylphosphonium pyridoxine derivative with five aromatic and aliphatic
aldehydes led to a series of mono- and bis-alkenyl substituted products. The reactions also demonstrated
unusual reactivity patterns leading to unexpected products, including a Z-shaped hyperconjugated structure
with trans-configuration for all three alkene fragments, and a tricyclic 9,10-dihydro-1H-[1,3]dioxino
[4,5-c]quinoline formed as a result of non-symmetric Wittig olefination followed by a rare type of
intramolecular cyclization. The obtained products represent prospective biologically active agents, while
one compound is a potential microenvironment- and interaction-sensitive molecular probe. |
ru_RU |
dc.language.iso |
ru |
ru_RU |
dc.subject |
Pyridoxine |
ru_RU |
dc.subject |
wittig reaction |
ru_RU |
dc.subject |
hydrolysis oxidation |
ru_RU |
dc.subject |
intramolecular cyclization |
ru_RU |
dc.title |
Wittig reactions of a bis-triphenylphosphonium pyridoxine derivative |
ru_RU |
dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|