| Форма представления | Статьи в российских журналах и сборниках |
| Год публикации | 2017 |
|
Антипин Игорь Сергеевич, автор
Ахметзянова Залия Валиевна, автор
Коновалов Александр Иванович, автор
Соловьева Светлана Евгеньевна, автор
|
| Другие авторы |
Р. Р. Кашапов, А. М. Бекмухаметова, Л. Я. Захарова, Е. В. Попова |
|
Ахметзянова Залия Валиевна, автор
|
| Библиографическое описание на языке оригинала |
Ruslan R.Kashapov, Alina M.Bekmukhametova, Lucia Ya.Zakharova, Zaliya V. Akhmetzyanova, Elena V.Popova,Svetlana E.Solovieva, Igor S.Antipin, Alexander I.Konovalov, Self-Aggregation and Solubilizing Properties of the Supramolecular System Based on Azobenzenesulfonate Calix[4]arene and CTAB, 2017, v.10 (4-5), p.454-459 |
| Аннотация |
The intermolecular interaction of azobenzenesulfonate calix[4]arene with cationic surfactant CTAB was studied
by a complex of physicochemical methods. The influence of calix[4]arene:CTAB ratio on the form of the aggregates
in their mixed composition in the aqueous medium was determined. Single-layer vesicles are formed in the equimolar
azobenzenesulfonate calix[4]arene-CTAB mixture. A threefold increase in the proportion of CTAB leads to the enlarge-ment of vesicles, namely, an increase in numbers of bilayers. Spectrophotometry was used to select the conditions for
binding of the hydrophobic spectral probe Sudan I by this mixed composition. The fluorescence spectroscopy estab-lishes dependence between the amount of encapsulated Rhodamine B and the size of the vesicle. Thus, the azobenzene-sulfonate calix[4]arene?CTAB system is capable for binding of both hydrophobic and hydrophilic substrates depending
on the components ratio. |
| Ключевые слова |
Calixarene, surfactant, Sudan I, Rodamine B, solubilization, aggregation. |
| Название журнала |
Макрогетероциклы
|
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=182385 |
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Антипин Игорь Сергеевич |
ru_RU |
| dc.contributor.author |
Ахметзянова Залия Валиевна |
ru_RU |
| dc.contributor.author |
Коновалов Александр Иванович |
ru_RU |
| dc.contributor.author |
Соловьева Светлана Евгеньевна |
ru_RU |
| dc.contributor.author |
Ахметзянова Залия Валиевна |
ru_RU |
| dc.date.accessioned |
2017-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2017-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2017 |
ru_RU |
| dc.identifier.citation |
Ruslan R.Kashapov, Alina M.Bekmukhametova, Lucia Ya.Zakharova, Zaliya V. Akhmetzyanova, Elena V.Popova,Svetlana E.Solovieva, Igor S.Antipin, Alexander I.Konovalov, Self-Aggregation and Solubilizing Properties of the Supramolecular System Based on Azobenzenesulfonate Calix[4]arene and CTAB, 2017, v.10 (4-5), p.454-459 |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=182385 |
ru_RU |
| dc.description.abstract |
Макрогетероциклы |
ru_RU |
| dc.description.abstract |
The intermolecular interaction of azobenzenesulfonate calix[4]arene with cationic surfactant CTAB was studied
by a complex of physicochemical methods. The influence of calix[4]arene:CTAB ratio on the form of the aggregates
in their mixed composition in the aqueous medium was determined. Single-layer vesicles are formed in the equimolar
azobenzenesulfonate calix[4]arene-CTAB mixture. A threefold increase in the proportion of CTAB leads to the enlarge-ment of vesicles, namely, an increase in numbers of bilayers. Spectrophotometry was used to select the conditions for
binding of the hydrophobic spectral probe Sudan I by this mixed composition. The fluorescence spectroscopy estab-lishes dependence between the amount of encapsulated Rhodamine B and the size of the vesicle. Thus, the azobenzene-sulfonate calix[4]arene?CTAB system is capable for binding of both hydrophobic and hydrophilic substrates depending
on the components ratio. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
Calixarene |
ru_RU |
| dc.subject |
surfactant |
ru_RU |
| dc.subject |
Sudan I |
ru_RU |
| dc.subject |
Rodamine B |
ru_RU |
| dc.subject |
solubilization |
ru_RU |
| dc.subject |
aggregation. |
ru_RU |
| dc.title |
Self-Aggregation and Solubilizing Properties of the Supramolecular System Based on Azobenzenesulfonate Calix[4]arene and CTAB |
ru_RU |
| dc.type |
Статьи в российских журналах и сборниках |
ru_RU |
|
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