| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2019 |
| Язык | английский |
|
Вагизов Фарит Габдулхакович, автор
Валимухаметова Алина Рестемовна, автор
Димиев Айрат Маратович, автор
Киямов Айрат Газинурович, автор
Ханнанов Артур Айдарович, автор
|
| Библиографическое описание на языке оригинала |
Direct Growth of the Oriented Nanocrystals of Gamma-Iron on Graphene Oxide Substrate. The Detailed Analysis of the Factors Affecting Unexpected Formation of the Gamma-Iron Phase / A. Khannanov [at al.] // New J. Chem. - 2019. - V.43, - P.12923-12931.
|
| Аннотация |
In bulk, face-centered gamma-iron exists only at temperatures above 917 ?C, returning back to body-centered alpha-iron upon cooling below this temperature. In this work, we report formation of the gamma-iron phase at temperatures significantly lower than the 917 ?C threshold in the form of nanoparticles. Moreover, the as-grown nanoparticles have specific orientation along the (002) plane as the result of the templating effect of the graphene oxide substrate. Also, we provide a complete account of the factors responsible for the formation of the gamma-phase. Namely, we demonstrate the role of the type of carbon substrate, and the effect of the temperature and time of annealing and the graphene oxide/iron ion ratio. We demonstrate that the gamma-phase is not formed when using three-dimensional forms of carbon, elucidating the “magic” role of graphene oxide in this process. |
| Ключевые слова |
Gamma-iron nanoparticles, graphene oxide substrate, X-ray, Mossbauer effect, SEM images |
| Название журнала |
NEW JOURNAL OF CHEMISTRY
|
| Ссылка для РПД |
http://dspace.kpfu.ru/xmlui/bitstream/handle/net/158237/F_Direct_Growth_of_the_Oriented_Nanocrystals_of_Gamma_Iron_on_Graphene_Oxide_Substrate.pdf?sequence=1&isAllowed=y
|
| URL |
https://pubs.rsc.org/en/content/articlelanding/2019/nj/c9nj02903f#!divAbstract |
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=206263 |
| Файлы ресурса | |
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Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Вагизов Фарит Габдулхакович |
ru_RU |
| dc.contributor.author |
Валимухаметова Алина Рестемовна |
ru_RU |
| dc.contributor.author |
Димиев Айрат Маратович |
ru_RU |
| dc.contributor.author |
Киямов Айрат Газинурович |
ru_RU |
| dc.contributor.author |
Ханнанов Артур Айдарович |
ru_RU |
| dc.date.accessioned |
2019-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2019-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2019 |
ru_RU |
| dc.identifier.citation |
Direct Growth of the Oriented Nanocrystals of Gamma-Iron on Graphene Oxide Substrate. The Detailed Analysis of the Factors Affecting Unexpected Formation of the Gamma-Iron Phase / A. Khannanov [at al.] // New J. Chem. - 2019. - V.43, - P.12923-12931.
|
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=206263 |
ru_RU |
| dc.description.abstract |
NEW JOURNAL OF CHEMISTRY |
ru_RU |
| dc.description.abstract |
In bulk, face-centered gamma-iron exists only at temperatures above 917 ?C, returning back to body-centered alpha-iron upon cooling below this temperature. In this work, we report formation of the gamma-iron phase at temperatures significantly lower than the 917 ?C threshold in the form of nanoparticles. Moreover, the as-grown nanoparticles have specific orientation along the (002) plane as the result of the templating effect of the graphene oxide substrate. Also, we provide a complete account of the factors responsible for the formation of the gamma-phase. Namely, we demonstrate the role of the type of carbon substrate, and the effect of the temperature and time of annealing and the graphene oxide/iron ion ratio. We demonstrate that the gamma-phase is not formed when using three-dimensional forms of carbon, elucidating the “magic” role of graphene oxide in this process. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
Gamma-iron nanoparticles |
ru_RU |
| dc.subject |
graphene oxide substrate |
ru_RU |
| dc.subject |
X-ray |
ru_RU |
| dc.subject |
Mossbauer effect |
ru_RU |
| dc.subject |
SEM images |
ru_RU |
| dc.title |
Direct Growth of the Oriented Nanocrystals of Gamma-Iron on Graphene Oxide Substrate. The Detailed Analysis of the Factors Affecting Unexpected Formation of the Gamma-Iron Phase |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
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