| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2019 |
| Язык | английский |
|
Бекмухамедов Гияз Эдуардович, автор
Герасимов Александр Владимирович, автор
Сухов Александр Вячеславович, автор
Хаяров Хасан Рафаэлевич, автор
Яхваров Дмитрий Григорьевич, автор
|
|
Василенко Ирина Владимировна, автор
Костюк Сергей Викторович, автор
|
| Библиографическое описание на языке оригинала |
Bekmukhamedov, G.E. Electrochemical Synthesis of Zirconium Pre-Catalysts for Homogeneous Ethylene Oligomerization / Bekmukhamedov, G.E.; Sukhov, A.V.; Kuchkaev, A.M.; Khayarov, K.R.; Gerasimov, A.V.; Vasilenko, I.V.; Kostjuk, S.V.; Yakhvarov, D.G. // Catalysts - 2019. - V. 9 (№ 12). - P. 1059-. |
| Аннотация |
The catalytic activity of electrochemically synthesized zirconium carboxylates was studied in the process of ethylene oligomerization. Zirconium carboxylates were electrochemically synthesized directly from metallic zirconium and corresponding carboxylic acids (acetic, octanoic and lauric). A comprehensive study (element analysis, nuclear magnetic resonance (NMR) and infrared (IR) spectroscopy, powder X-ray diffraction (PXRD)) of the synthesized zirconium carboxylates showed that these species contain bidentate carboxylate moieties. It was shown that obtained zirconium carboxylates, in combination with Et3Al2Cl3 (Al/Zr = 20), have a moderate activity of (7.6–9.9) × 103 molC2H4⋅molZr−1⋅h−1 in terms of ethylene oligomerization (at T = 80 ?C, p = 20 bar), leading to even-numbered C4–C10 linear alpha-olefins. |
| Ключевые слова |
electrochemical synthesis, zirconium carboxylate, ethylene oligomerization, pre-catalyst, linear alpha-olefins |
| Название журнала |
Catalysts
|
| Ссылка для РПД |
http://dspace.kpfu.ru/xmlui/bitstream/handle/net/152060/F_catalysts_09_01059_pervaya_stranica.pdf?sequence=1&isAllowed=y
|
| URL |
https://www.mdpi.com/2073-4344/9/12/1059/htm |
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=216672 |
| Файлы ресурса | |
|
|
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Бекмухамедов Гияз Эдуардович |
ru_RU |
| dc.contributor.author |
Герасимов Александр Владимирович |
ru_RU |
| dc.contributor.author |
Сухов Александр Вячеславович |
ru_RU |
| dc.contributor.author |
Хаяров Хасан Рафаэлевич |
ru_RU |
| dc.contributor.author |
Яхваров Дмитрий Григорьевич |
ru_RU |
| dc.contributor.author |
Василенко Ирина Владимировна |
ru_RU |
| dc.contributor.author |
Костюк Сергей Викторович |
ru_RU |
| dc.date.accessioned |
2019-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2019-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2019 |
ru_RU |
| dc.identifier.citation |
Bekmukhamedov, G.E. Electrochemical Synthesis of Zirconium Pre-Catalysts for Homogeneous Ethylene Oligomerization / Bekmukhamedov, G.E.; Sukhov, A.V.; Kuchkaev, A.M.; Khayarov, K.R.; Gerasimov, A.V.; Vasilenko, I.V.; Kostjuk, S.V.; Yakhvarov, D.G. // Catalysts - 2019. - V. 9 (№ 12). - P. 1059-. |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=216672 |
ru_RU |
| dc.description.abstract |
Catalysts |
ru_RU |
| dc.description.abstract |
The catalytic activity of electrochemically synthesized zirconium carboxylates was studied in the process of ethylene oligomerization. Zirconium carboxylates were electrochemically synthesized directly from metallic zirconium and corresponding carboxylic acids (acetic, octanoic and lauric). A comprehensive study (element analysis, nuclear magnetic resonance (NMR) and infrared (IR) spectroscopy, powder X-ray diffraction (PXRD)) of the synthesized zirconium carboxylates showed that these species contain bidentate carboxylate moieties. It was shown that obtained zirconium carboxylates, in combination with Et3Al2Cl3 (Al/Zr = 20), have a moderate activity of (7.6–9.9) × 103 molC2H4⋅molZr−1⋅h−1 in terms of ethylene oligomerization (at T = 80 ?C, p = 20 bar), leading to even-numbered C4–C10 linear alpha-olefins. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
electrochemical synthesis |
ru_RU |
| dc.subject |
zirconium carboxylate |
ru_RU |
| dc.subject |
ethylene oligomerization |
ru_RU |
| dc.subject |
pre-catalyst |
ru_RU |
| dc.subject |
linear alpha-olefins |
ru_RU |
| dc.title |
Electrochemical Synthesis of Zirconium Pre-Catalysts for Homogeneous Ethylene Oligomerization |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
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