КФУ. Карточка публикации. Ni-based complexes in selective ethylene oligomerization processes

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NI-BASED COMPLEXES IN SELECTIVE ETHYLENE OLIGOMERIZATION PROCESSES

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2020

Язык

английский

Авторы, сотрудники КФУ

Бекмухамедов Гияз Эдуардович, автор

Кучкаев Айдар Маратович, автор

Сухов Александр Вячеславович, автор

Яхваров Дмитрий Григорьевич, автор

Авторы, аспиранты КФУ

Кучкаев Айдар Маратович, автор

Библиографическое описание на языке оригинала

Bekmukhamedov, G.E.; Sukhov, A.V.; Kuchkaev, A.M.; Yakhvarov, D.G. Ni-based complexes in selective ethylene oligomerization processes. Catalysts. 2020, 10, 498. DOI:10.3390/catal10050498

Аннотация

Linear alpha-olefins are widely used in the petrochemical industry and the world demand for these compounds increases annually. At present, the main method for producing linear alpha-olefins is the homogeneous catalytic ethylene oligomerization. This review presents modern nickel catalysts for this process, mainly systems for obtaining of one of the most demanded oligomer—1-butene—which is used for the production of linear low density polyethylene (LLDPE) and high density polyethylene (HDPE). The dependence of the catalytic performance on the composition and the structure of the used activated complexes, the electronic and coordination states of the nickel center was considered.

Ключевые слова

homogeneous catalysis, ethylene oligomerization, nickel complexes, catalytic activity, selectivity, imine ligands, organophosphorus ligands, carbene ligands

Название журнала

Catalysts

URL

https://ex.kpfu.ru/owa/redir.aspx?C=whk6cRwW4Khg2tRdNy_Xk1rcC-Eum4kTVAWPLS6En9MoMF7-bwjYCA..&URL=https%3a%2f%2fwww.mdpi.com%2f2073-4344%2f10%2f5%2f498

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https://repository.kpfu.ru/?p_id=233305

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Бекмухамедов Гияз Эдуардович	ru_RU
dc.contributor.author	Кучкаев Айдар Маратович	ru_RU
dc.contributor.author	Сухов Александр Вячеславович	ru_RU
dc.contributor.author	Яхваров Дмитрий Григорьевич	ru_RU
dc.contributor.author	Кучкаев Айдар Маратович	ru_RU
dc.date.accessioned	2020-01-01T00:00:00Z	ru_RU
dc.date.available	2020-01-01T00:00:00Z	ru_RU
dc.date.issued	2020	ru_RU
dc.identifier.citation	Bekmukhamedov, G.E.; Sukhov, A.V.; Kuchkaev, A.M.; Yakhvarov, D.G. Ni-based complexes in selective ethylene oligomerization processes. Catalysts. 2020, 10, 498. DOI:10.3390/catal10050498	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=233305	ru_RU
dc.description.abstract	Catalysts	ru_RU
dc.description.abstract	Linear alpha-olefins are widely used in the petrochemical industry and the world demand for these compounds increases annually. At present, the main method for producing linear alpha-olefins is the homogeneous catalytic ethylene oligomerization. This review presents modern nickel catalysts for this process, mainly systems for obtaining of one of the most demanded oligomer—1-butene—which is used for the production of linear low density polyethylene (LLDPE) and high density polyethylene (HDPE). The dependence of the catalytic performance on the composition and the structure of the used activated complexes, the electronic and coordination states of the nickel center was considered.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	homogeneous catalysis	ru_RU
dc.subject	ethylene oligomerization	ru_RU
dc.subject	nickel complexes	ru_RU
dc.subject	catalytic activity	ru_RU
dc.subject	selectivity	ru_RU
dc.subject	imine ligands	ru_RU
dc.subject	organophosphorus ligands	ru_RU
dc.subject	carbene ligands	ru_RU
dc.title	Ni-based complexes in selective ethylene oligomerization processes	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU