| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2020 |
|
Антипин Игорь Сергеевич, автор
Бурилов Владимир Александрович, автор
Евтюгин Владимир Геннадьевич, автор
Исламов Даут Ринатович, автор
Миронова Диана Александровна, автор
Осин Юрий Николаевич, автор
Соловьева Светлана Евгеньевна, автор
Султанова Эльза Дамировна, автор
Усачев Константин Сергеевич, автор
|
|
Гафиатуллин Булат Халимович, автор
|
| Библиографическое описание на языке оригинала |
V.A. Burilov, B.H.Gafiatullin, D.A. Mironova, E.D. Sultanova, V. Evtugyn, Y. Osin, D. Islamov, K. Usachev, S. Solovieva I. Antipin, Amphiphilic Pd (II)-NHC complexes on 1,3-alternate p-tertbutylthiacalix[4]arene platform: synthesis and catalytic activities in coupling and hydrogenation reactions. European Journal of Organic Chemistry., 2020 (2020), 2153 |
| Аннотация |
Herein we report the first example of amphiphilic PdII?NHC complexes on the thiacalix[4]arene backbone in 1,3‐alternate configuration. Relative catalytic activity of synthesized PdII?NHC complexes in Suzuki?Miyaura coupling of haloarenes with phenylboronic acid was studied. A combination of micellar and metallocomplex catalysis was observed in Suzuki?Miyaura coupling upon going from pure DMF to water/DMF 3:1: the 2‐fold increase of conversion of 4‐bromoanisole unlike pure DMF was found. Interesting feature was found using chloroarene in DMF/water: the reaction selectivity changed from heterocoupling to homo coupling of phenylboronic acid. PdII?NHC complexes demonstrated a high activity in model hydrogenation reaction of p‐nitrophenol using sodium borohydride. The most lipophilic PdII?NHC complex was found to be most active, which can be attributed with additional p‐nitrophenol preconcentration in the aggregates due to larger hydrophobic capacity of macrocycle. |
| Ключевые слова |
NHC complex, thiacalix[4]arene, suzuki coupling, micellar catalysis, catalytic hydrogenation |
| URL |
https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejoc.202000059 |
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=249805 |
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Антипин Игорь Сергеевич |
ru_RU |
| dc.contributor.author |
Бурилов Владимир Александрович |
ru_RU |
| dc.contributor.author |
Евтюгин Владимир Геннадьевич |
ru_RU |
| dc.contributor.author |
Исламов Даут Ринатович |
ru_RU |
| dc.contributor.author |
Миронова Диана Александровна |
ru_RU |
| dc.contributor.author |
Осин Юрий Николаевич |
ru_RU |
| dc.contributor.author |
Соловьева Светлана Евгеньевна |
ru_RU |
| dc.contributor.author |
Султанова Эльза Дамировна |
ru_RU |
| dc.contributor.author |
Усачев Константин Сергеевич |
ru_RU |
| dc.contributor.author |
Гафиатуллин Булат Халимович |
ru_RU |
| dc.date.accessioned |
2020-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2020-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2020 |
ru_RU |
| dc.identifier.citation |
V.A. Burilov, B.H.Gafiatullin, D.A. Mironova, E.D. Sultanova, V. Evtugyn, Y. Osin, D. Islamov, K. Usachev, S. Solovieva I. Antipin, Amphiphilic Pd (II)-NHC complexes on 1,3-alternate p-tertbutylthiacalix[4]arene platform: synthesis and catalytic activities in coupling and hydrogenation reactions. European Journal of Organic Chemistry., 2020 (2020), 2153 |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=249805 |
ru_RU |
| dc.description.abstract |
Herein we report the first example of amphiphilic PdII?NHC complexes on the thiacalix[4]arene backbone in 1,3‐alternate configuration. Relative catalytic activity of synthesized PdII?NHC complexes in Suzuki?Miyaura coupling of haloarenes with phenylboronic acid was studied. A combination of micellar and metallocomplex catalysis was observed in Suzuki?Miyaura coupling upon going from pure DMF to water/DMF 3:1: the 2‐fold increase of conversion of 4‐bromoanisole unlike pure DMF was found. Interesting feature was found using chloroarene in DMF/water: the reaction selectivity changed from heterocoupling to homo coupling of phenylboronic acid. PdII?NHC complexes demonstrated a high activity in model hydrogenation reaction of p‐nitrophenol using sodium borohydride. The most lipophilic PdII?NHC complex was found to be most active, which can be attributed with additional p‐nitrophenol preconcentration in the aggregates due to larger hydrophobic capacity of macrocycle. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
NHC complex |
ru_RU |
| dc.subject |
thiacalix[4]arene |
ru_RU |
| dc.subject |
suzuki coupling |
ru_RU |
| dc.subject |
micellar catalysis |
ru_RU |
| dc.subject |
catalytic hydrogenation |
ru_RU |
| dc.title |
Amphiphilic Pd (II)-NHC complexes on 1,3-alternate p-tertbutylthiacalix[4]arene platform: synthesis and catalytic activities in coupling and hydrogenation reactions |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
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