КФУ. Карточка публикации. Nonylphenol ethoxylate surfactants modified by carboxyl groups for foam EOR at high-salinity conditions

КАЗАНСКИЙ
ФЕДЕРАЛЬНЫЙ УНИВЕРСИТЕТ

RUS

- EN
- 中文
- ES

NONYLPHENOL ETHOXYLATE SURFACTANTS MODIFIED BY CARBOXYL GROUPS FOR FOAM EOR AT HIGH-SALINITY CONDITIONS

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2021

Язык

английский

Авторы, сотрудники КФУ

Варфоломеев Михаил Алексеевич, автор

Жанбосынова Шинар , автор

Жарков Дмитрий Андреевич, автор

Павельев Роман Сергеевич, автор

Сайфуллин Эмиль Ринатович, автор

Библиографическое описание на языке оригинала

Saifullin E.R, Zhanbossynova S, Zharkov D.A, Nonylphenol ethoxylate surfactants modified by carboxyl groups for foam EOR at high-salinity conditions//Energies. - 2021. - Vol.14, Is.24. - Art. №8205.

Аннотация

High mineralization of water complicates the use of foam in reservoir conditions. Anionic–nonionic surfactants are one of the best candidates for these conditions since they have both high surface activity and salt tolerance. One of the ways to obtain anionic–nonionic surfactants is to modify nonionic surfactants by an anionic group. The type of the group and its chemical structure can strongly affect the properties of the surfactant. In this work, widely-produced nonionic surfactant nonylphenol (12) ethoxylate (NP12EO) was modified by new types of carboxylic groups through the implementation of maleic (NP12EO-MA) and succinic (NP12EO-SA) anhydrides with different saturation levels. The main objectives of this work were to compare synthesized surfactants with nonionic precursor and to reveal the influence of unsaturated bonds in the carboxyl group on the properties of the foam. NaCl concentration up to 20 wt% was used to simulate high mineralization conditions, as well as to assess the effect of unsaturated bonds on foam properties. Synthesized anionic–nonionic surfactants retained surfactant solubility and long-term stability in high-salinity water, but have better foaming ability, as well as higher apparent viscosity, in porous media. The presence of an unsaturated bond in NP12EO-MA surfactant lowers foaming ability at high mineralization.

Ключевые слова

foam, surfactant, carboxylated ethoxylated nonylphenol, chemical EOR, high-salinity water

Название журнала

Energies

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85120811867&doi=10.3390%2fen14248205&partnerID=40&md5=cd83e5741340371023a505b5e27051b0

Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку

https://repository.kpfu.ru/?p_id=261925

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Варфоломеев Михаил Алексеевич	ru_RU
dc.contributor.author	Жанбосынова Шинар	ru_RU
dc.contributor.author	Жарков Дмитрий Андреевич	ru_RU
dc.contributor.author	Павельев Роман Сергеевич	ru_RU
dc.contributor.author	Сайфуллин Эмиль Ринатович	ru_RU
dc.date.accessioned	2021-01-01T00:00:00Z	ru_RU
dc.date.available	2021-01-01T00:00:00Z	ru_RU
dc.date.issued	2021	ru_RU
dc.identifier.citation	Saifullin E.R, Zhanbossynova S, Zharkov D.A, Nonylphenol ethoxylate surfactants modified by carboxyl groups for foam EOR at high-salinity conditions//Energies. - 2021. - Vol.14, Is.24. - Art. №8205.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=261925	ru_RU
dc.description.abstract	Energies	ru_RU
dc.description.abstract	High mineralization of water complicates the use of foam in reservoir conditions. Anionic–nonionic surfactants are one of the best candidates for these conditions since they have both high surface activity and salt tolerance. One of the ways to obtain anionic–nonionic surfactants is to modify nonionic surfactants by an anionic group. The type of the group and its chemical structure can strongly affect the properties of the surfactant. In this work, widely-produced nonionic surfactant nonylphenol (12) ethoxylate (NP12EO) was modified by new types of carboxylic groups through the implementation of maleic (NP12EO-MA) and succinic (NP12EO-SA) anhydrides with different saturation levels. The main objectives of this work were to compare synthesized surfactants with nonionic precursor and to reveal the influence of unsaturated bonds in the carboxyl group on the properties of the foam. NaCl concentration up to 20 wt% was used to simulate high mineralization conditions, as well as to assess the effect of unsaturated bonds on foam properties. Synthesized anionic–nonionic surfactants retained surfactant solubility and long-term stability in high-salinity water, but have better foaming ability, as well as higher apparent viscosity, in porous media. The presence of an unsaturated bond in NP12EO-MA surfactant lowers foaming ability at high mineralization.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	foam	ru_RU
dc.subject	surfactant	ru_RU
dc.subject	carboxylated ethoxylated nonylphenol	ru_RU
dc.subject	chemical EOR	ru_RU
dc.subject	high-salinity water	ru_RU
dc.title	Nonylphenol ethoxylate surfactants modified by carboxyl groups for foam EOR at high-salinity conditions	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU