КФУ. Карточка публикации. Dual Promotion-Inhibition Effects of Novel Ethylenediaminetetraacetic Acid Bisamides on Methane Hydrate Formation for Gas Storage and Flow Assurance Applications

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DUAL PROMOTION-INHIBITION EFFECTS OF NOVEL ETHYLENEDIAMINETETRAACETIC ACID BISAMIDES ON METHANE HYDRATE FORMATION FOR GAS STORAGE AND FLOW ASSURANCE APPLICATIONS

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2021

Язык

английский

Авторы, сотрудники КФУ

Варфоломеев Михаил Алексеевич, автор

Павельев Роман Сергеевич, автор

Семенов Матвей Егорович, автор

Библиографическое описание на языке оригинала

Pavelyev R.S, Gainullin S.E, Semenov M.E, Dual Promotion-Inhibition Effects of Novel Ethylenediaminetetraacetic Acid Bisamides on Methane Hydrate Formation for Gas Storage and Flow Assurance Applications//Energy and Fuels. - 2021. - Vol., Is.. - .

Аннотация

Surfactants have been reported as the most efficient gas hydrate promoters (GHPs) for gas storage and transportation; however, slow kinetics of nucleation and growth of hydrate crystals and foam formation during hydrate dissociation severely impact their applications. Here, a new class of chemical additives based on ethylenediaminetetraacetic acid bisamides was developed to control methane hydrate formation for gas storage and flow assurance applications. Synthesized molecules contain both polar fragments (carboxyl and amide groups) and hydrophobic alkyl groups with different sizes and branching. The obtained results revealed that bisamides with short alkyl chains (n-propyl and isopropyl) promoted the formation of methane hydrate and significantly reduced foam stability during hydrate decomposition compared to sodium dodecyl sulfate (SDS). Moreover, by increasing the length of the alkyl substituent up to propyl, the nucleation time increased. However, the conversion of gas to hydrate escalated remarkably. A transition from promotion to inhibition properties is observed with a further increase in the alkyl chain from propyl to butyl. Nevertheless, bisamides with hexyl groups showed surfactant properties, which is responsible for their poor promotion efficiency. In addition, the studied compounds practically do not form foam and are less toxic compared to SDS as a well-known GHP. The results of this study can be useful for the design and development of effective additives for gas storage and flow assurance applications.

Ключевые слова

Gas storage, flow assurance, gas hydrate promoter, kinetic hydrate inhibitor, cytotoxicity

Название журнала

Energy and Fuels

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85122037375&doi=10.1021%2facs.energyfuels.1c03381&partnerID=40&md5=6ee9e709cfb46f07b8587150053b82f9

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https://repository.kpfu.ru/?p_id=262583

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Варфоломеев Михаил Алексеевич	ru_RU
dc.contributor.author	Павельев Роман Сергеевич	ru_RU
dc.contributor.author	Семенов Матвей Егорович	ru_RU
dc.date.accessioned	2021-01-01T00:00:00Z	ru_RU
dc.date.available	2021-01-01T00:00:00Z	ru_RU
dc.date.issued	2021	ru_RU
dc.identifier.citation	Pavelyev R.S, Gainullin S.E, Semenov M.E, Dual Promotion-Inhibition Effects of Novel Ethylenediaminetetraacetic Acid Bisamides on Methane Hydrate Formation for Gas Storage and Flow Assurance Applications//Energy and Fuels. - 2021. - Vol., Is.. - .	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=262583	ru_RU
dc.description.abstract	Energy and Fuels	ru_RU
dc.description.abstract	Surfactants have been reported as the most efficient gas hydrate promoters (GHPs) for gas storage and transportation; however, slow kinetics of nucleation and growth of hydrate crystals and foam formation during hydrate dissociation severely impact their applications. Here, a new class of chemical additives based on ethylenediaminetetraacetic acid bisamides was developed to control methane hydrate formation for gas storage and flow assurance applications. Synthesized molecules contain both polar fragments (carboxyl and amide groups) and hydrophobic alkyl groups with different sizes and branching. The obtained results revealed that bisamides with short alkyl chains (n-propyl and isopropyl) promoted the formation of methane hydrate and significantly reduced foam stability during hydrate decomposition compared to sodium dodecyl sulfate (SDS). Moreover, by increasing the length of the alkyl substituent up to propyl, the nucleation time increased. However, the conversion of gas to hydrate escalated remarkably. A transition from promotion to inhibition properties is observed with a further increase in the alkyl chain from propyl to butyl. Nevertheless, bisamides with hexyl groups showed surfactant properties, which is responsible for their poor promotion efficiency. In addition, the studied compounds practically do not form foam and are less toxic compared to SDS as a well-known GHP. The results of this study can be useful for the design and development of effective additives for gas storage and flow assurance applications.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Gas storage	ru_RU
dc.subject	flow assurance	ru_RU
dc.subject	gas hydrate promoter	ru_RU
dc.subject	kinetic hydrate inhibitor	ru_RU
dc.subject	cytotoxicity	ru_RU
dc.title	Dual Promotion-Inhibition Effects of Novel Ethylenediaminetetraacetic Acid Bisamides on Methane Hydrate Formation for Gas Storage and Flow Assurance Applications	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU