Форма представления | Статьи в зарубежных журналах и сборниках |
Год публикации | 2020 |
Язык | английский |
|
Шулятьев Алексей Александрович, автор
|
Библиографическое описание на языке оригинала |
Kiselev V.D., Kolesnikova A.O., Dinikaev I.E., Shulyatiev A.A., Klimovitskii A.E., Kornilov D.A. / Diels-Alder reaction rate in the solid state and the evidence of the location of molecular complexes between the reagents on the reaction pathway // International Journal of Chemical Kinetics. – 2021. – V.53. – P.207-212. |
Аннотация |
The rate of reactions in the solid phase with uniform grinding of crystals of dienes, anthracene, and 9,10-dimethylanthracene, with dienophiles, tetracyanoethylene, N-phenylmaleimide, and 4-phenyl-1,2,4-triazoline-3,5-dione, has been studied. It was shown that, despite the high difference in the reaction rates in solution, the rates of these reactions in the solid phase are much closer. For anthracene-tetracyanoethylene and 9,10-dimethylanthracene-tetracyanoethylene pairs, it was concluded that their intermolecular complexes are on the reaction pathway. |
Ключевые слова |
Diels-Alder reaction, kinetics, molecular complex, solid state |
Название журнала |
International Journal of Chemical Kinetics
|
URL |
https://onlinelibrary.wiley.com/doi/epdf/10.1002/kin.21434?src=getftr |
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https://repository.kpfu.ru/?p_id=271796 |
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Поле DC |
Значение |
Язык |
dc.contributor.author |
Шулятьев Алексей Александрович |
ru_RU |
dc.date.accessioned |
2020-01-01T00:00:00Z |
ru_RU |
dc.date.available |
2020-01-01T00:00:00Z |
ru_RU |
dc.date.issued |
2020 |
ru_RU |
dc.identifier.citation |
Kiselev V.D., Kolesnikova A.O., Dinikaev I.E., Shulyatiev A.A., Klimovitskii A.E., Kornilov D.A. / Diels-Alder reaction rate in the solid state and the evidence of the location of molecular complexes between the reagents on the reaction pathway // International Journal of Chemical Kinetics. – 2021. – V.53. – P.207-212. |
ru_RU |
dc.identifier.uri |
https://repository.kpfu.ru/?p_id=271796 |
ru_RU |
dc.description.abstract |
International Journal of Chemical Kinetics |
ru_RU |
dc.description.abstract |
The rate of reactions in the solid phase with uniform grinding of crystals of dienes, anthracene, and 9,10-dimethylanthracene, with dienophiles, tetracyanoethylene, N-phenylmaleimide, and 4-phenyl-1,2,4-triazoline-3,5-dione, has been studied. It was shown that, despite the high difference in the reaction rates in solution, the rates of these reactions in the solid phase are much closer. For anthracene-tetracyanoethylene and 9,10-dimethylanthracene-tetracyanoethylene pairs, it was concluded that their intermolecular complexes are on the reaction pathway. |
ru_RU |
dc.language.iso |
ru |
ru_RU |
dc.subject |
Diels-Alder reaction |
ru_RU |
dc.subject |
kinetics |
ru_RU |
dc.subject |
molecular complex |
ru_RU |
dc.subject |
solid state |
ru_RU |
dc.title |
Diels-Alder reaction rate in the solid state and the evidence of the location of molecular complexes between the reagents on the reaction pathway |
ru_RU |
dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|