КФУ. Карточка публикации. Diels-Alder reaction rate in the solid state and the evidence of the location of molecular complexes between the reagents on the reaction pathway

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DIELS-ALDER REACTION RATE IN THE SOLID STATE AND THE EVIDENCE OF THE LOCATION OF MOLECULAR COMPLEXES BETWEEN THE REAGENTS ON THE REACTION PATHWAY

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2020

Язык

английский

Авторы, сотрудники КФУ

Шулятьев Алексей Александрович, автор

Библиографическое описание на языке оригинала

Kiselev V.D., Kolesnikova A.O., Dinikaev I.E., Shulyatiev A.A., Klimovitskii A.E., Kornilov D.A. / Diels-Alder reaction rate in the solid state and the evidence of the location of molecular complexes between the reagents on the reaction pathway // International Journal of Chemical Kinetics. – 2021. – V.53. – P.207-212.

Аннотация

The rate of reactions in the solid phase with uniform grinding of crystals of dienes, anthracene, and 9,10-dimethylanthracene, with dienophiles, tetracyanoethylene, N-phenylmaleimide, and 4-phenyl-1,2,4-triazoline-3,5-dione, has been studied. It was shown that, despite the high difference in the reaction rates in solution, the rates of these reactions in the solid phase are much closer. For anthracene-tetracyanoethylene and 9,10-dimethylanthracene-tetracyanoethylene pairs, it was concluded that their intermolecular complexes are on the reaction pathway.

Ключевые слова

Diels-Alder reaction, kinetics, molecular complex, solid state

Название журнала

International Journal of Chemical Kinetics

URL

https://onlinelibrary.wiley.com/doi/epdf/10.1002/kin.21434?src=getftr

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https://repository.kpfu.ru/?p_id=271796

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Шулятьев Алексей Александрович	ru_RU
dc.date.accessioned	2020-01-01T00:00:00Z	ru_RU
dc.date.available	2020-01-01T00:00:00Z	ru_RU
dc.date.issued	2020	ru_RU
dc.identifier.citation	Kiselev V.D., Kolesnikova A.O., Dinikaev I.E., Shulyatiev A.A., Klimovitskii A.E., Kornilov D.A. / Diels-Alder reaction rate in the solid state and the evidence of the location of molecular complexes between the reagents on the reaction pathway // International Journal of Chemical Kinetics. – 2021. – V.53. – P.207-212.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=271796	ru_RU
dc.description.abstract	International Journal of Chemical Kinetics	ru_RU
dc.description.abstract	The rate of reactions in the solid phase with uniform grinding of crystals of dienes, anthracene, and 9,10-dimethylanthracene, with dienophiles, tetracyanoethylene, N-phenylmaleimide, and 4-phenyl-1,2,4-triazoline-3,5-dione, has been studied. It was shown that, despite the high difference in the reaction rates in solution, the rates of these reactions in the solid phase are much closer. For anthracene-tetracyanoethylene and 9,10-dimethylanthracene-tetracyanoethylene pairs, it was concluded that their intermolecular complexes are on the reaction pathway.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Diels-Alder reaction	ru_RU
dc.subject	kinetics	ru_RU
dc.subject	molecular complex	ru_RU
dc.subject	solid state	ru_RU
dc.title	Diels-Alder reaction rate in the solid state and the evidence of the location of molecular complexes between the reagents on the reaction pathway	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU