КФУ. Карточка публикации. Layer-by-layer combination of MWCNTs and poly(ferulic acid) as electrochemical platform for hesperidin quantification

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LAYER-BY-LAYER COMBINATION OF MWCNTS AND POLY(FERULIC ACID) AS ELECTROCHEMICAL PLATFORM FOR HESPERIDIN QUANTIFICATION

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2023

Язык

английский

Авторы, сотрудники КФУ

Зиятдинова Гузель Камилевна, автор

Другие авторы

Мухарлямова Айсылу , автор

Фицев Игорь , автор

Авторы, аспиранты КФУ

Якупова Эльвира Наилевна, автор

Библиографическое описание на языке оригинала

Yakupova, E. Layer-by-layer combination of MWCNTs and poly(ferulic acid) as electrochemical platform for hesperidin quantification / E. Yakupova, A. Mukharlyamova, I. Fitsev, G. Ziyatdinova // Biosensors. – 2023. – V. 13. – № 5.- Article 500. – 19 p.

Аннотация

The electrochemical polymerization of suitable monomers is a powerful way to create voltammetric sensors with improved responses to a target analyte. Nonconductive polymers based on phenolic acids were successfully combined with carbon nanomaterials to obtain sufficient conductivity and high surface area of the electrode. Glassy carbon electrodes (GCE) modified with multi-walled carbon nanotubes (MWCNTs) and electropolymerized ferulic acid (FA) were developed for the sensitive quantification of hesperidin. The optimized conditions of FA electropolymerization in basic medium (15 cycles from −0.2 to 1.0 V at 100 mV s−1 in 250 ?mol L−1 monomer solution in 0.1 mol L−1 NaOH) were found using the voltammetric response of hesperidin. The polymer-modified electrode exhibited a high electroactive surface area (1.14 ? 0.05 cm2 vs. 0.75 ? 0.03 and 0.089 ? 0.003 cm2 for MWCNTs/GCE and bare GCE, respectively) and decreased in the charge transfer resistance (21.4 ? 0.9 kΩ vs. 72 ? 3 kΩ for bare GCE). Under optimized conditions, hesperidin linear dynamic ranges of 0.025–1.0 and 1.0–10 ?mol L−1 with a detection limit of 7.0 nmol L−1 were achieved, which were the best ones among those reported to date. The developed electrode was tested on orange juice and compared with chromatography.

Ключевые слова

Voltammetric sensors, chemically modified electrodes, carbon nanomaterials, electropolymerization, phenolic acids, flavanones, hesperidin

Название журнала

Biosensors

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85160299774&doi=10.3390%2fbios13050500&partnerID=40&md5=faced03c873b2d1bad905acc7906ada0

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https://repository.kpfu.ru/?p_id=282385

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Зиятдинова Гузель Камилевна	ru_RU
dc.contributor.author	Мухарлямова Айсылу	ru_RU
dc.contributor.author	Фицев Игорь	ru_RU
dc.contributor.author	Якупова Эльвира Наилевна	ru_RU
dc.date.accessioned	2023-01-01T00:00:00Z	ru_RU
dc.date.available	2023-01-01T00:00:00Z	ru_RU
dc.date.issued	2023	ru_RU
dc.identifier.citation	Yakupova, E. Layer-by-layer combination of MWCNTs and poly(ferulic acid) as electrochemical platform for hesperidin quantification / E. Yakupova, A. Mukharlyamova, I. Fitsev, G. Ziyatdinova // Biosensors. – 2023. – V. 13. – № 5.- Article 500. – 19 p.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=282385	ru_RU
dc.description.abstract	Biosensors	ru_RU
dc.description.abstract	The electrochemical polymerization of suitable monomers is a powerful way to create voltammetric sensors with improved responses to a target analyte. Nonconductive polymers based on phenolic acids were successfully combined with carbon nanomaterials to obtain sufficient conductivity and high surface area of the electrode. Glassy carbon electrodes (GCE) modified with multi-walled carbon nanotubes (MWCNTs) and electropolymerized ferulic acid (FA) were developed for the sensitive quantification of hesperidin. The optimized conditions of FA electropolymerization in basic medium (15 cycles from −0.2 to 1.0 V at 100 mV s−1 in 250 ?mol L−1 monomer solution in 0.1 mol L−1 NaOH) were found using the voltammetric response of hesperidin. The polymer-modified electrode exhibited a high electroactive surface area (1.14 ? 0.05 cm2 vs. 0.75 ? 0.03 and 0.089 ? 0.003 cm2 for MWCNTs/GCE and bare GCE, respectively) and decreased in the charge transfer resistance (21.4 ? 0.9 kΩ vs. 72 ? 3 kΩ for bare GCE). Under optimized conditions, hesperidin linear dynamic ranges of 0.025–1.0 and 1.0–10 ?mol L−1 with a detection limit of 7.0 nmol L−1 were achieved, which were the best ones among those reported to date. The developed electrode was tested on orange juice and compared with chromatography.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Voltammetric sensors	ru_RU
dc.subject	chemically modified electrodes	ru_RU
dc.subject	carbon nanomaterials	ru_RU
dc.subject	electropolymerization	ru_RU
dc.subject	phenolic acids	ru_RU
dc.subject	flavanones	ru_RU
dc.subject	hesperidin	ru_RU
dc.title	Layer-by-layer combination of MWCNTs and poly(ferulic acid) as electrochemical platform for hesperidin quantification	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU