КФУ. Карточка публикации. 2(5H)-Furanone Azides in the Synthesis of Iminophosphoranes and Amines

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2(5H)-FURANONE AZIDES IN THE SYNTHESIS OF IMINOPHOSPHORANES AND AMINES

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2024

Язык

русский

Авторы, сотрудники КФУ

Сайгитбаталова Елена Шириповна, автор

Библиографическое описание на языке оригинала

Saigitbatalova E.S. 2(5H)-Furanone Azides in the Synthesis of Iminophosphoranes and Amines / E.S. Saigitbatalova, D.R. Fedorova, O.A. Lodochnikova, D. R. Islamov , I. D. Shutilov , K. S. Usachev, A. R. Kurbangalieva // Russ J Gen Chem - 2024. 94, p 835–847.

Аннотация

The synthesis and characterization of previously unknown azides, iminophosphoranes and amines from commercially available mucochloric and mucobromic acids is reported. The reaction of 5-alkoxy-3,4-dihalo-2(5H)-furanones with sodium azide resulted in the regioselective formation of furanone 4-azidoderivatives. A series of novel iminophosphoranes was obtained from the reaction of corresponding azides with triphenylphosphine. Reduction of iminophosphoranes with stannous chloride dihydrate led to the heterocycles, possessing an amino group at the C4 carbon atom of the unsaturated γ-lactone ring.

Ключевые слова

2(5H)-furanone, unsaturated lactone, organic azide, iminophosphorane, Staudinger reaction, amine

Название журнала

Russian Journal of General Chemistry

URL

https://link.springer.com/article/10.1134/S1070363224040108#citeas

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https://repository.kpfu.ru/?p_id=301771

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Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Сайгитбаталова Елена Шириповна	ru_RU
dc.date.accessioned	2024-01-01T00:00:00Z	ru_RU
dc.date.available	2024-01-01T00:00:00Z	ru_RU
dc.date.issued	2024	ru_RU
dc.identifier.citation	Saigitbatalova E.S. 2(5H)-Furanone Azides in the Synthesis of Iminophosphoranes and Amines / E.S. Saigitbatalova, D.R. Fedorova, O.A. Lodochnikova, D. R. Islamov , I. D. Shutilov , K. S. Usachev, A. R. Kurbangalieva // Russ J Gen Chem - 2024. 94, p 835–847.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=301771	ru_RU
dc.description.abstract	Russian Journal of General Chemistry	ru_RU
dc.description.abstract	The synthesis and characterization of previously unknown azides, iminophosphoranes and amines from commercially available mucochloric and mucobromic acids is reported. The reaction of 5-alkoxy-3,4-dihalo-2(5H)-furanones with sodium azide resulted in the regioselective formation of furanone 4-azidoderivatives. A series of novel iminophosphoranes was obtained from the reaction of corresponding azides with triphenylphosphine. Reduction of iminophosphoranes with stannous chloride dihydrate led to the heterocycles, possessing an amino group at the C4 carbon atom of the unsaturated γ-lactone ring.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	2(5H)-furanone	ru_RU
dc.subject	unsaturated lactone	ru_RU
dc.subject	organic azide	ru_RU
dc.subject	iminophosphorane	ru_RU
dc.subject	Staudinger reaction	ru_RU
dc.subject	amine	ru_RU
dc.title	2(5H)-Furanone Azides in the Synthesis of Iminophosphoranes and Amines	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU