| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2024 |
| Язык | русский |
|
Исламов Даут Ринатович, автор
Курбангалиева Альмира Рафаэловна, автор
Лодочникова Ольга Александровна, автор
Сайгитбаталова Елена Шириповна, автор
Усачев Константин Сергеевич, автор
Федорова Диляра Ришатовна, автор
|
|
Шутилов Илья Денисович, автор
|
| Библиографическое описание на языке оригинала |
Saigitbatalova E.S. 2(5H)-Furanone Azides in the Synthesis of Iminophosphoranes and Amines / E.S. Saigitbatalova, D.R. Fedorova, O.A. Lodochnikova, D. R. Islamov , I. D. Shutilov , K. S. Usachev, A. R. Kurbangalieva // Russ J Gen Chem - 2024. 94, p 835–847. |
| Аннотация |
The synthesis and characterization of previously unknown azides, iminophosphoranes and amines from commercially available mucochloric and mucobromic acids is reported. The reaction of 5-alkoxy-3,4-dihalo-2(5H)-furanones with sodium azide resulted in the regioselective formation of furanone 4-azidoderivatives. A series of novel iminophosphoranes was obtained from the reaction of corresponding azides with triphenylphosphine. Reduction of iminophosphoranes with stannous chloride dihydrate led to the heterocycles, possessing an amino group at the C4 carbon atom of the unsaturated γ-lactone ring. |
| Ключевые слова |
2(5H)-furanone, unsaturated lactone, organic azide, iminophosphorane, Staudinger reaction, amine |
| Название журнала |
Russian Journal of General Chemistry
|
| URL |
https://link.springer.com/article/10.1134/S1070363224040108#citeas |
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=301771 |
| Файлы ресурса | |
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Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Исламов Даут Ринатович |
ru_RU |
| dc.contributor.author |
Курбангалиева Альмира Рафаэловна |
ru_RU |
| dc.contributor.author |
Лодочникова Ольга Александровна |
ru_RU |
| dc.contributor.author |
Сайгитбаталова Елена Шириповна |
ru_RU |
| dc.contributor.author |
Усачев Константин Сергеевич |
ru_RU |
| dc.contributor.author |
Федорова Диляра Ришатовна |
ru_RU |
| dc.contributor.author |
Шутилов Илья Денисович |
ru_RU |
| dc.date.accessioned |
2024-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2024-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2024 |
ru_RU |
| dc.identifier.citation |
Saigitbatalova E.S. 2(5H)-Furanone Azides in the Synthesis of Iminophosphoranes and Amines / E.S. Saigitbatalova, D.R. Fedorova, O.A. Lodochnikova, D. R. Islamov , I. D. Shutilov , K. S. Usachev, A. R. Kurbangalieva // Russ J Gen Chem - 2024. 94, p 835–847. |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=301771 |
ru_RU |
| dc.description.abstract |
Russian Journal of General Chemistry |
ru_RU |
| dc.description.abstract |
The synthesis and characterization of previously unknown azides, iminophosphoranes and amines from commercially available mucochloric and mucobromic acids is reported. The reaction of 5-alkoxy-3,4-dihalo-2(5H)-furanones with sodium azide resulted in the regioselective formation of furanone 4-azidoderivatives. A series of novel iminophosphoranes was obtained from the reaction of corresponding azides with triphenylphosphine. Reduction of iminophosphoranes with stannous chloride dihydrate led to the heterocycles, possessing an amino group at the C4 carbon atom of the unsaturated γ-lactone ring. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
2(5H)-furanone |
ru_RU |
| dc.subject |
unsaturated lactone |
ru_RU |
| dc.subject |
organic azide |
ru_RU |
| dc.subject |
iminophosphorane |
ru_RU |
| dc.subject |
Staudinger reaction |
ru_RU |
| dc.subject |
amine |
ru_RU |
| dc.title |
2(5H)-Furanone Azides in the Synthesis of Iminophosphoranes and Amines |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
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