| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2024 |
| Язык | английский |
|
Еремин Михаил Васильевич, автор
|
| Библиографическое описание на языке оригинала |
Eremin M.V., Spin-dependent crystal field on f-electrons as a consequence of spin-orbit coupling renormalization due to exchange-covalent bonds with ligands//Applied Magnetic Resonance. - 2024. - V. 55.-P. 1233-1239. |
| Аннотация |
The problem of renormalization of the spin–orbit interaction operator of electrons
of partially filled nf-shells due to exchange-covalent bonds with surrounding ligands
has been solved. It is found that along with the change of the standard spin–orbit
interaction parameter, new energy operators are generated, which can be interpreted
as a spin-dependent crystal field operator. Simple formulas are obtained that allows
to calculate its parameters via covalence parameters and overlap integrals. Numerical
evaluations have been performed for multiplets Tb3+(f 8)7F6 and Er3+(f 11)4I15∕2
in fluorides with cubic symmetry. Calculated parameters were found to be of the order of 10% relative to the standard crystal field parameters. |
| Ключевые слова |
Spin-dependent crystal field, exchange-covalent bonds effect |
| Название журнала |
Applied Magnetic Resonance
|
| URL |
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85201397621&doi=10.1007%2fs00723-024-01701-8&partnerID=40&md5=a859f2e4454e8d19594167d4a6a5a1fa |
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=304976 |
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Еремин Михаил Васильевич |
ru_RU |
| dc.date.accessioned |
2024-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2024-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2024 |
ru_RU |
| dc.identifier.citation |
Eremin M.V., Spin-dependent crystal field on f-electrons as a consequence of spin-orbit coupling renormalization due to exchange-covalent bonds with ligands//Applied Magnetic Resonance. - 2024. - V. 55.-P. 1233-1239. |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=304976 |
ru_RU |
| dc.description.abstract |
Applied Magnetic Resonance |
ru_RU |
| dc.description.abstract |
The problem of renormalization of the spin–orbit interaction operator of electrons
of partially filled nf-shells due to exchange-covalent bonds with surrounding ligands
has been solved. It is found that along with the change of the standard spin–orbit
interaction parameter, new energy operators are generated, which can be interpreted
as a spin-dependent crystal field operator. Simple formulas are obtained that allows
to calculate its parameters via covalence parameters and overlap integrals. Numerical
evaluations have been performed for multiplets Tb3+(f 8)7F6 and Er3+(f 11)4I15∕2
in fluorides with cubic symmetry. Calculated parameters were found to be of the order of 10% relative to the standard crystal field parameters. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
Spin-dependent crystal field |
ru_RU |
| dc.subject |
exchange-covalent bonds effect |
ru_RU |
| dc.title |
Spin-dependent crystal field on f-electrons as a consequence of spin?orbit coupling renormalization due to exchange-covalent bonds with ligands |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
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