КФУ. Карточка публикации. hermal analysis of charge-transfer complex formed by nitrogen dioxide and substituted calix[4]arene: characterization of complexation reversibility

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HERMAL ANALYSIS OF CHARGE-TRANSFER COMPLEX FORMED BY NITROGEN DIOXIDE AND SUBSTITUTED CALIX[4]ARENE: CHARACTERIZATION OF COMPLEXATION REVERSIBILITY

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2012

Авторы, сотрудники КФУ

Горбачук Валерий Виленович, автор

Зиганшин Марат Ахмедович, автор

Сафина Гульназ Дамировна, автор

Авторы, студенты КФУ

Хабибуллин Амир Асгатович, автор

Библиографическое описание на языке оригинала

Khabibullin, A.A. Thermal analysis of charge-transfer complex formed by nitrogen dioxide and substituted calix[4]arene: characterization of complexation reversibility / Amir A. Khabibullin, Goulnaz D. Safina, Marat A. Ziganshin, Valery V. Gorbatchuk // J. Therm. Anal. Calorim. - 2012. - V.110, No. 3. - P.1309-1313

Аннотация

J THERM ANAL CALORIM

Ключевые слова

Calixarene, Charge-transfer complex, Nitrogen dioxide detection, STA-EGA analysis

Название журнала

J THERM ANAL CALORIM

URL

http://www.springerlink.com/content/23q39037830882u7/fulltext.pdf

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https://repository.kpfu.ru/?p_id=38200

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Горбачук Валерий Виленович	ru_RU
dc.contributor.author	Зиганшин Марат Ахмедович	ru_RU
dc.contributor.author	Сафина Гульназ Дамировна	ru_RU
dc.contributor.author	Хабибуллин Амир Асгатович	ru_RU
dc.date.accessioned	2012-01-01T00:00:00Z	ru_RU
dc.date.available	2012-01-01T00:00:00Z	ru_RU
dc.date.issued	2012	ru_RU
dc.identifier.citation	Khabibullin, A.A. Thermal analysis of charge-transfer complex formed by nitrogen dioxide and substituted calix[4]arene: characterization of complexation reversibility / Amir A. Khabibullin, Goulnaz D. Safina, Marat A. Ziganshin, Valery V. Gorbatchuk // J. Therm. Anal. Calorim. - 2012. - V.110, No. 3. - P.1309-1313	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=38200	ru_RU
dc.description.abstract	J THERM ANAL CALORIM	ru_RU
dc.description.abstract	J THERM ANAL CALORIM	ru_RU
dc.description.abstract	Simultaneous thermal analysis with evolved gas analysis (STA-EGA) was used to study the ability of 1,3-alternate conformer of tert-butylcalix[4]arene with four n-propoxy substituents (1) to be applied for detection of nitrogen dioxide in reversible sensors. Solid calixarene 1 forms an intensively colored charge-transfer complex (CTC) with gaseous NO2/N2O4. Using the STA-EGA method, the nature and conditions of CTC bleaching were characterized, including the conditions of its reversible change of color from white to dark blue and back at CTC formation and decomposition. For this, the thermal stability of CTC and its regeneration products were studied. This, together with the ion thermograms for evolved gases, gives the information on the oxidation of 1 by nitrogen dioxide if present.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Calixarene	ru_RU
dc.subject	Charge-transfer complex	ru_RU
dc.subject	Nitrogen dioxide detection	ru_RU
dc.subject	STA-EGA analysis	ru_RU
dc.title	hermal analysis of charge-transfer complex formed by nitrogen dioxide and substituted calix[4]arene: characterization of complexation reversibility	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU