КФУ. Карточка публикации. Anti-sieve effect in guest inclusion by thiacalix[4]arene giving a surge in thermal stability of its clathrates prepared by solid-phase guest exchange

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ANTI-SIEVE EFFECT IN GUEST INCLUSION BY THIACALIX[4]ARENE GIVING A SURGE IN THERMAL STABILITY OF ITS CLATHRATES PREPARED BY SOLID-PHASE GUEST EXCHANGE

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2014

Авторы, сотрудники КФУ

Галялтдинов Шамиль Фазлурович, автор

Горбачук Валерий Виленович, автор

Зиганшин Марат Ахмедович, автор

Другие авторы

A.T. Gubaidullin; S.G. Vyshnevsky; O.I. Kalchenko.

Авторы, аспиранты КФУ

Галялтдинов Шамиль Фазлурович, автор

Библиографическое описание на языке оригинала

V. Gorbatchuk, Sh. Galyaltdinov, M. Ziganshin, A. Gubaidullin, O. Kalchenko, S. Vyshnevsky // Anti-sieve effect in guest inclusion by thiacalix[4]arene giving a surge in thermal stability of its clathrates prepared by solid-phase guest exchange // CrystEngComm. – 2014, 16 (18), 3781 - 3787

Аннотация

CrystEngComm

Ключевые слова

Thiacalixarene, clathrate, thermal stability, solid-phase exchange, X-ray powder diffractometry, anti-sieve effect.

Название журнала

CrystEngComm

URL

http://pubs.rsc.org/en/Content/ArticleLanding/2014/CE/c3ce42304b#!divAbstract

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https://repository.kpfu.ru/?p_id=86482

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Галялтдинов Шамиль Фазлурович	ru_RU
dc.contributor.author	Горбачук Валерий Виленович	ru_RU
dc.contributor.author	Зиганшин Марат Ахмедович	ru_RU
dc.contributor.author	Галялтдинов Шамиль Фазлурович	ru_RU
dc.date.accessioned	2014-01-01T00:00:00Z	ru_RU
dc.date.available	2014-01-01T00:00:00Z	ru_RU
dc.date.issued	2014	ru_RU
dc.identifier.citation	V. Gorbatchuk, Sh. Galyaltdinov, M. Ziganshin, A. Gubaidullin, O. Kalchenko, S. Vyshnevsky // Anti-sieve effect in guest inclusion by thiacalix[4]arene giving a surge in thermal stability of its clathrates prepared by solid-phase guest exchange // CrystEngComm. – 2014, 16 (18), 3781 - 3787	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=86482	ru_RU
dc.description.abstract	CrystEngComm	ru_RU
dc.description.abstract	CrystEngComm	ru_RU
dc.description.abstract	An unusual bell-like relationship between guest size parameter and properties of thiacalix[4]arene (1) clathrates was observed, which is a source of their very high thermal stability. For this, calixarene 1 clathrates were prepared in binary ?solid host ? guest vapor? system and by solid-phase exchange with guests of various molecular structure. The clathrates were studied by thermal analysis and X-ray powder diffractometry. Calixarene 1 was found to have a specific anti-sieve effect excluding smaller guest compounds, while having a preference for the larger ones. This effect may be avoided using solid-phase guest exchange in clathrate preparation, but it contributes much to the thermal stability of exchange products.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Thiacalixarene	ru_RU
dc.subject	clathrate	ru_RU
dc.subject	thermal stability	ru_RU
dc.subject	solid-phase exchange	ru_RU
dc.subject	X-ray powder diffractometry	ru_RU
dc.subject	anti-sieve effect.	ru_RU
dc.title	Anti-sieve effect in guest inclusion by thiacalix[4]arene giving a surge in thermal stability of its clathrates prepared by solid-phase guest exchange	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU