КФУ. Карточка публикации. Solid-contact potentiometric sensor based on polyaniline and unsubstituted pillar[5]arene

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SOLID-CONTACT POTENTIOMETRIC SENSOR BASED ON POLYANILINE AND UNSUBSTITUTED PILLAR[5]ARENE

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2015

Язык

русский

Авторы, сотрудники КФУ

Будников Герман Константинович, автор

Евтюгин Геннадий Артурович, автор

Стойков Иван Иванович, автор

Стойкова Екатерина Евгеньевна, автор

Авторы, аспиранты КФУ

Сорвин Михаил Игоревич, автор

Шурпик Дмитрий Николаевич, автор

Библиографическое описание на языке оригинала

Stoikova, E.E. Solid-contact potentiometric sensor based on polyaniline and unsubstituted pillar[5]arene [Text] / E.E. Stoikova, M.I. Sorvin, D.N. Shurpik, H.C. Budnikov, I.I. Stoikov, G.A. Evtugyn // Electroanalysis. - 2015. - V.27. - P.440-449.

Аннотация

A novel potentiometric sensor based on screen-printed carbon electrode covered with electropolymerized polyaniline and unsubstituted pillar[5]arene as ionophore has been developed and tested in potentiometric measurements of pH and metal ions. The introduction of pillar[5]arene improved the reversibility of the pH response in the range from 2.0 to 9.0 with the slope of 45 mV/pH. Among metal cations, the response to Fe(3+) and Ag(+)ions was referred to PANI redox conversion whereas the signal toward Cu(2+) in the range from 1.0x10-6 to 1.0x10-2 M (limit of detection 3.0x10-7 M) to specific interaction with the macrocycle.

Ключевые слова

Potentiometric sensor, Solid-contact sensor, Pillar[5]arene, Polyaniline, Electropolymerization

Название журнала

ELECTROANAL

URL

http://onlinelibrary.wiley.com/doi/10.1002/elan.201400494/abstract

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https://repository.kpfu.ru/?p_id=99358

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Будников Герман Константинович	ru_RU
dc.contributor.author	Евтюгин Геннадий Артурович	ru_RU
dc.contributor.author	Стойков Иван Иванович	ru_RU
dc.contributor.author	Стойкова Екатерина Евгеньевна	ru_RU
dc.contributor.author	Сорвин Михаил Игоревич	ru_RU
dc.contributor.author	Шурпик Дмитрий Николаевич	ru_RU
dc.date.accessioned	2015-01-01T00:00:00Z	ru_RU
dc.date.available	2015-01-01T00:00:00Z	ru_RU
dc.date.issued	2015	ru_RU
dc.identifier.citation	Stoikova, E.E. Solid-contact potentiometric sensor based on polyaniline and unsubstituted pillar[5]arene [Text] / E.E. Stoikova, M.I. Sorvin, D.N. Shurpik, H.C. Budnikov, I.I. Stoikov, G.A. Evtugyn // Electroanalysis. - 2015. - V.27. - P.440-449.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=99358	ru_RU
dc.description.abstract	ELECTROANAL	ru_RU
dc.description.abstract	A novel potentiometric sensor based on screen-printed carbon electrode covered with electropolymerized polyaniline and unsubstituted pillar[5]arene as ionophore has been developed and tested in potentiometric measurements of pH and metal ions. The introduction of pillar[5]arene improved the reversibility of the pH response in the range from 2.0 to 9.0 with the slope of 45 mV/pH. Among metal cations, the response to Fe(3+) and Ag(+)ions was referred to PANI redox conversion whereas the signal toward Cu(2+) in the range from 1.0x10-6 to 1.0x10-2 M (limit of detection 3.0x10-7 M) to specific interaction with the macrocycle.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Potentiometric sensor	ru_RU
dc.subject	Solid-contact sensor	ru_RU
dc.subject	Pillar[5]arene	ru_RU
dc.subject	Polyaniline	ru_RU
dc.subject	Electropolymerization	ru_RU
dc.title	Solid-contact potentiometric sensor based on polyaniline and unsubstituted pillar[5]arene	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU