KFU. Card publication. Electrochemical Mediated Synthesis of Silver Nanoparticles in Solution

KAZAN
FEDERAL UNIVERSITY

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ELECTROCHEMICAL MEDIATED SYNTHESIS OF SILVER NANOPARTICLES IN SOLUTION

Form of presentation

Articles in international journals and collections

Year of publication

2015

Язык

английский

Authors, employees of KFU

Ziganshina Albina Yulduzovna, author

Bibliographic description in the original language

G. R. Nasretdinova, R. R. Fazleeva, R. K. Mukhitova, I. R. Nizameev, M. K. Kadirov, A. Yu. Ziganshina, V. V. Yanilkin / Electrochemical Mediated Synthesis of Silver Nanoparticles in Solution // Russ. J. Electrochem. – 2015. – 51. – 1029–1040.

Annotation

Methyl viologen MV2+ and tetraviologen calix[4]resorcinol MVCA-C 8+ 5 with n-pentyl substituents in the resorcinol rings at potentials of MV2+/MV?+ and MVCA-C 8+ 5 /MVCA-C 4?+ 5 redox couples proved to be effective mediators of the electrochemical reduction of Ag+ ions in DMF/0.1 M Bu4NPF6. The potentiostatic nondiaphragm electrolysis at controlled mediator reduction potentials at room temperature using an Ag anode as an in situ supplier of Ag+ led to the formation of metallic silver nanoparticles in solution. The only resulting effect of electrolysis was the quantitative transfer of the metal anode into the metal nanoparticles in solution. In the case of MV2+, the nanoparticles aggregated into larger particles. MVCA-CC 8+ 5 serves not only as a mediator, but also, to some extent, as a stabilizer of silver nanoparticles and can be recorded by a set of experimental methods.

Keywords

electrochemical synthesis, silver nanoparticles, mediator, methyl viologen, viologen calix[4]resorcinol

The name of the journal

RUSSIAN JOURNAL OF ELECTROCHEMISTRY

URL

https://link.springer.com/article/10.1134/S1023193515110129#citeas

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=262932&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Ziganshina Albina Yulduzovna	ru_RU
dc.date.accessioned	2015-01-01T00:00:00Z	ru_RU
dc.date.available	2015-01-01T00:00:00Z	ru_RU
dc.date.issued	2015	ru_RU
dc.identifier.citation	G. R. Nasretdinova, R. R. Fazleeva, R. K. Mukhitova, I. R. Nizameev, M. K. Kadirov, A. Yu. Ziganshina, V. V. Yanilkin / Electrochemical Mediated Synthesis of Silver Nanoparticles in Solution // Russ. J. Electrochem. – 2015. – 51. – 1029–1040.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=262932&p_lang=2	ru_RU
dc.description.abstract	RUSSIAN JOURNAL OF ELECTROCHEMISTRY	ru_RU
dc.description.abstract	Methyl viologen MV2+ and tetraviologen calix[4]resorcinol MVCA-C 8+ 5 with n-pentyl substituents in the resorcinol rings at potentials of MV2+/MV?+ and MVCA-C 8+ 5 /MVCA-C 4?+ 5 redox couples proved to be effective mediators of the electrochemical reduction of Ag+ ions in DMF/0.1 M Bu4NPF6. The potentiostatic nondiaphragm electrolysis at controlled mediator reduction potentials at room temperature using an Ag anode as an in situ supplier of Ag+ led to the formation of metallic silver nanoparticles in solution. The only resulting effect of electrolysis was the quantitative transfer of the metal anode into the metal nanoparticles in solution. In the case of MV2+, the nanoparticles aggregated into larger particles. MVCA-CC 8+ 5 serves not only as a mediator, but also, to some extent, as a stabilizer of silver nanoparticles and can be recorded by a set of experimental methods.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	electrochemical synthesis	ru_RU
dc.subject	silver nanoparticles	ru_RU
dc.subject	mediator	ru_RU
dc.subject	methyl viologen	ru_RU
dc.subject	viologen calix[4]resorcinol	ru_RU
dc.title	Electrochemical Mediated Synthesis of Silver Nanoparticles in Solution	ru_RU
dc.type	Articles in international journals and collections	ru_RU