KFU. Card publication. EPR study of clusters of rare-earth ions in mixed fluoride crystals

KAZAN
FEDERAL UNIVERSITY

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EPR STUDY OF CLUSTERS OF RARE-EARTH IONS IN MIXED FLUORIDE CRYSTALS

Form of presentation

Articles in Russian journals and collections

Year of publication

2014

Authors, employees of KFU

Aminov Linar Kashifovich, author

Gafurov Marat Revgerovich, author

Kurkin Igor Nikolaevich, author

Rodionov Aleksandr Aleksandrovich, author

Bibliographic description in the original language

L. K. Aminov, M. R. Gafurov, I. N. Kurkin, A. A. Rodionov. EPR study of clusters of rare-earth ions in mixed fluoride crystals. Optics and Spectroscopy. May 2014, Volume 116, Issue 5, pp 773-776.

Annotation

The EPR spectra of the (BaF2)1 − x (CeF3) x system are studied for the concentrations x = 0, 0.001, 0.002, 0.005, 0.01, and 0.02. The appearance of new tetragonal centers is detected beginning from x = 0.002, the intensity of these centers being maximal at x = 0.01. The (CaF2)1 − x − y (CeF3) x (YF3) y double solutions with x = 0.001 and y from 0 to 0.02 are also studied. In addition to the ordinary tetragonal center, beginning from y = 0.001, a new tetragonal center appears with the same structure as in the previously studied mixed crystals based on BaF2?namely, the Ce3+-□-R3+ chain elongated along the fourfold axis substitutes the Ca2+-Ca2+-Ca2+ and Ba2+-Ba2+-Ba2+ chains in regular CaF2 and BaF2 crystals (□ is the cation vacancy, and R3+ is the Ce3+, La3+, or Y3+ trivalent ion).

Keywords

EPR, ESR, mixed crytals, Optoelectronics, Plasmonics and Optical Devices

The name of the journal

OPT SPECTROSC+

URL

http://link.springer.com/article/10.1134%2FS0030400X14050038

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=86576&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Aminov Linar Kashifovich	ru_RU
dc.contributor.author	Gafurov Marat Revgerovich	ru_RU
dc.contributor.author	Kurkin Igor Nikolaevich	ru_RU
dc.contributor.author	Rodionov Aleksandr Aleksandrovich	ru_RU
dc.date.accessioned	2014-01-01T00:00:00Z	ru_RU
dc.date.available	2014-01-01T00:00:00Z	ru_RU
dc.date.issued	2014	ru_RU
dc.identifier.citation	L. K. Aminov, M. R. Gafurov, I. N. Kurkin, A. A. Rodionov. EPR study of clusters of rare-earth ions in mixed fluoride crystals. Optics and Spectroscopy. May 2014, Volume 116, Issue 5, pp 773-776.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=86576&p_lang=2	ru_RU
dc.description.abstract	OPT SPECTROSC+	ru_RU
dc.description.abstract	The EPR spectra of the (BaF2)1 − x (CeF3) x system are studied for the concentrations x = 0, 0.001, 0.002, 0.005, 0.01, and 0.02. The appearance of new tetragonal centers is detected beginning from x = 0.002, the intensity of these centers being maximal at x = 0.01. The (CaF2)1 − x − y (CeF3) x (YF3) y double solutions with x = 0.001 and y from 0 to 0.02 are also studied. In addition to the ordinary tetragonal center, beginning from y = 0.001, a new tetragonal center appears with the same structure as in the previously studied mixed crystals based on BaF2?namely, the Ce3+-□-R3+ chain elongated along the fourfold axis substitutes the Ca2+-Ca2+-Ca2+ and Ba2+-Ba2+-Ba2+ chains in regular CaF2 and BaF2 crystals (□ is the cation vacancy, and R3+ is the Ce3+, La3+, or Y3+ trivalent ion).	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	EPR	ru_RU
dc.subject	ESR	ru_RU
dc.subject	mixed crytals	ru_RU
dc.subject	Optoelectronics	ru_RU
dc.subject	Plasmonics and Optical Devices	ru_RU
dc.title	EPR study of clusters of rare-earth ions in mixed fluoride crystals	ru_RU
dc.type	Articles in Russian journals and collections	ru_RU