| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2015 |
| Язык | английский |
|
Гатауллина Карина Всеволодовна, автор
Горбачук Валерий Виленович, автор
Стойков Иван Иванович, автор
|
|
Губайдуллин Айдар Тимергалеевич, автор
|
|
Гатауллина Карина Всеволодовна, автор
|
| Библиографическое описание на языке оригинала |
Gataullina, K. V. Twice as smart behavior of tert-butylthiacalix[4]arene derivative in glassy and crystalline form / K. V. Gataullina, M.Ziganshin, I. Stoikov, A. T. Gubaidullin, V.V. Gorbatchuk, // Physical Chemistry Chemical Physics. - 2015. - V.17.- N24. - P.15887-15895. |
| Аннотация |
A studied tert-butylthiacalix[4]arene derivative with four N-(2-acetoxyethyl)carbamoylmethoxy substituents
on its lower rim in partial-cone configuration (calixarene 1) can remember its previous treatment in three
essentially different ways by the formation either of a molecular glass or two metastable polymorphs after
heating or the removal of an included guest molecule. Guest-induced memory is very selective with a
polymorph created only after the release of a few included guests among a large series of those studied
and is detected via an exothermic transition. Along with ordinary properties, like glass transition, curing and
cold crystallization, the molecular glass from 1 is selective due to its ability to crystallize in solvent vapors
and vapor mixtures over a well-defined concentration range. Being cooperative, this property may be used
for the visual detection of ethanol content in water solution when it reaches a threshold value. |
| Ключевые слова |
molecular glass, smart materials, calixarene, thermal analysis |
| Название журнала |
PHYS CHEM CHEM PHYS
|
| URL |
http://pubs.rsc.org/en/content/articlepdf/2015/cp/c5cp02042e |
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=107727 |
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Гатауллина Карина Всеволодовна |
ru_RU |
| dc.contributor.author |
Горбачук Валерий Виленович |
ru_RU |
| dc.contributor.author |
Стойков Иван Иванович |
ru_RU |
| dc.contributor.author |
Губайдуллин Айдар Тимергалеевич |
ru_RU |
| dc.contributor.author |
Гатауллина Карина Всеволодовна |
ru_RU |
| dc.date.accessioned |
2015-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2015-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2015 |
ru_RU |
| dc.identifier.citation |
Gataullina, K. V. Twice as smart behavior of tert-butylthiacalix[4]arene derivative in glassy and crystalline form / K. V. Gataullina, M.Ziganshin, I. Stoikov, A. T. Gubaidullin, V.V. Gorbatchuk, // Physical Chemistry Chemical Physics. - 2015. - V.17.- N24. - P.15887-15895. |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=107727 |
ru_RU |
| dc.description.abstract |
PHYS CHEM CHEM PHYS |
ru_RU |
| dc.description.abstract |
A studied tert-butylthiacalix[4]arene derivative with four N-(2-acetoxyethyl)carbamoylmethoxy substituents
on its lower rim in partial-cone configuration (calixarene 1) can remember its previous treatment in three
essentially different ways by the formation either of a molecular glass or two metastable polymorphs after
heating or the removal of an included guest molecule. Guest-induced memory is very selective with a
polymorph created only after the release of a few included guests among a large series of those studied
and is detected via an exothermic transition. Along with ordinary properties, like glass transition, curing and
cold crystallization, the molecular glass from 1 is selective due to its ability to crystallize in solvent vapors
and vapor mixtures over a well-defined concentration range. Being cooperative, this property may be used
for the visual detection of ethanol content in water solution when it reaches a threshold value. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
molecular glass |
ru_RU |
| dc.subject |
smart materials |
ru_RU |
| dc.subject |
calixarene |
ru_RU |
| dc.subject |
thermal analysis |
ru_RU |
| dc.title |
Twice as smart behavior of tert-butylthiacalix[4]arene derivative in glassy and crystalline form |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
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