КФУ. Карточка публикации. Synthesis and spectroscopic characterization of Ru(II) and Sn(IV)-porphyrins supramolecular complexes

КАЗАНСКИЙ
ФЕДЕРАЛЬНЫЙ УНИВЕРСИТЕТ

RUS

- EN
- 中文
- ES

SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF RU(II) AND SN(IV)-PORPHYRINS SUPRAMOLECULAR COMPLEXES

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2015

Язык

английский

Авторы, сотрудники КФУ

Ходов Илья Анатольевич, автор

Библиографическое описание на языке оригинала

Synthesis and spectroscopic characterization of Ru(II) and Sn(IV)-porphyrins supramolecular complexes

Аннотация

Synthesis and NMR studies of Ru(II) and Sn(IV) tetraphenylporphyrins supramolecular complexes were carried out. The diffusion coefficients of the complexes, porphyrinates, and solvents were determined by DOSY NMR spectroscopy. By the method of spectrophotometric titration a binding ability of Ru(II) tetraphenylporphyrin towards 4-(imidazol-1-yl)-phenol was investigated, stability constant of resulting complexes and concentration intervals of their existence were defined. Crown Copyright ? 2014 Published by Elsevier B.V. All rights reserved.

Ключевые слова

DOSY, COSY, NMR.Axial coordination, Organic substrate, Ru(II) porphyrins, Sn(IV) porphyrins, Supramolecular complexes.

Название журнала

JOURNAL OF MOLECULAR STRUCTURE

Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку

https://repository.kpfu.ru/?p_id=120986

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Ходов Илья Анатольевич	ru_RU
dc.date.accessioned	2015-01-01T00:00:00Z	ru_RU
dc.date.available	2015-01-01T00:00:00Z	ru_RU
dc.date.issued	2015	ru_RU
dc.identifier.citation	Synthesis and spectroscopic characterization of Ru(II) and Sn(IV)-porphyrins supramolecular complexes	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=120986	ru_RU
dc.description.abstract	JOURNAL OF MOLECULAR STRUCTURE	ru_RU
dc.description.abstract	Synthesis and NMR studies of Ru(II) and Sn(IV) tetraphenylporphyrins supramolecular complexes were carried out. The diffusion coefficients of the complexes, porphyrinates, and solvents were determined by DOSY NMR spectroscopy. By the method of spectrophotometric titration a binding ability of Ru(II) tetraphenylporphyrin towards 4-(imidazol-1-yl)-phenol was investigated, stability constant of resulting complexes and concentration intervals of their existence were defined. Crown Copyright ? 2014 Published by Elsevier B.V. All rights reserved.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	DOSY	ru_RU
dc.subject	COSY	ru_RU
dc.subject	NMR.Axial coordination	ru_RU
dc.subject	Organic substrate	ru_RU
dc.subject	Ru(II) porphyrins	ru_RU
dc.subject	Sn(IV) porphyrins	ru_RU
dc.subject	Supramolecular complexes.	ru_RU
dc.title	Synthesis and spectroscopic characterization of Ru(II) and Sn(IV)-porphyrins supramolecular complexes	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU