| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2017 |
| Язык | английский |
|
Коновалов Александр Иванович, автор
Морозова Юлия Эрнестовна, автор
Шалаева Яна Викторовна, автор
|
|
кадиров марсил кахирович, автор
Казакова Элла Хатибовна, автор
Низамеев Ирек Рашатович, автор
Сякаев Виктор Васильевич, автор
|
|
Шуматбаева Алина Марселовна, автор
|
| Библиографическое описание на языке оригинала |
Yana V. Shalaeva, Supramolecular nanoscale systems based on amphiphilic tetramethylensulfonatocalix[4]resorcinarenes and cationic polyelectrolyte with controlled guest molecule binding/ Yana V. Shalaeva, Ju E. Morozova, V. V. Syakaev, E. Kh Kazakova, A. M. Ermakova, I. R. Nizameev, M. K. Kadirov, A. I. Konovalov. // Supramol. Chem., 2017, V 29, N4, 278-289
DOI: 10.1080/10610278.2016.1219034 |
| Аннотация |
The water-soluble tetramethylensulfonatocalix[4]resorcinarene with methyl (C1) and pentyl (C5)
substitutes on the lower rim forms colloid nanoscale aggregates with poly(diallyldimethylammonium
chloride) (PDDA) in aqueous solutions. The size and stability of nanoparticles depend on
concentrations of the components and their ratio in the 'calixarene-polymer' system. Ternary
supramolecular complexes «polymer–macrocycle–guest molecule L-tryptophan (Trp) in conditions
of spontaneous pH (3.80 and 4.78 for C1-PDDA and C5-PDDA systems, respectively) in an aqueous
solution and in phosphate buffer (pH 7) were investigated by fluorescence method. The addition
of the third component – PDDA – to the «non-aggregated C1–Trp» associates leads to the release
of Trp in all studied conditions. The possibility of the «binding–release» process of L-tryptophan in
«C5–Trp» associates after PDDA addition in the ternary complex is achieved. |
| Ключевые слова |
Supramolecular complex polymer-macrocycle; calix[4]resorcinarene; nanoscale aggregates;
l-tryptophan; fluorescence |
| Название журнала |
Supramolecular Chemistry
|
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=139074 |
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Коновалов Александр Иванович |
ru_RU |
| dc.contributor.author |
Морозова Юлия Эрнестовна |
ru_RU |
| dc.contributor.author |
Шалаева Яна Викторовна |
ru_RU |
| dc.contributor.author |
кадиров марсил кахирович |
ru_RU |
| dc.contributor.author |
Казакова Элла Хатибовна |
ru_RU |
| dc.contributor.author |
Низамеев Ирек Рашатович |
ru_RU |
| dc.contributor.author |
Сякаев Виктор Васильевич |
ru_RU |
| dc.contributor.author |
Шуматбаева Алина Марселовна |
ru_RU |
| dc.date.accessioned |
2017-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2017-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2017 |
ru_RU |
| dc.identifier.citation |
Yana V. Shalaeva, Supramolecular nanoscale systems based on amphiphilic tetramethylensulfonatocalix[4]resorcinarenes and cationic polyelectrolyte with controlled guest molecule binding/ Yana V. Shalaeva, Ju E. Morozova, V. V. Syakaev, E. Kh Kazakova, A. M. Ermakova, I. R. Nizameev, M. K. Kadirov, A. I. Konovalov. // Supramol. Chem., 2017, V 29, N4, 278-289
DOI: 10.1080/10610278.2016.1219034 |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=139074 |
ru_RU |
| dc.description.abstract |
Supramolecular Chemistry |
ru_RU |
| dc.description.abstract |
The water-soluble tetramethylensulfonatocalix[4]resorcinarene with methyl (C1) and pentyl (C5)
substitutes on the lower rim forms colloid nanoscale aggregates with poly(diallyldimethylammonium
chloride) (PDDA) in aqueous solutions. The size and stability of nanoparticles depend on
concentrations of the components and their ratio in the 'calixarene-polymer' system. Ternary
supramolecular complexes «polymer–macrocycle–guest molecule L-tryptophan (Trp) in conditions
of spontaneous pH (3.80 and 4.78 for C1-PDDA and C5-PDDA systems, respectively) in an aqueous
solution and in phosphate buffer (pH 7) were investigated by fluorescence method. The addition
of the third component – PDDA – to the «non-aggregated C1–Trp» associates leads to the release
of Trp in all studied conditions. The possibility of the «binding–release» process of L-tryptophan in
«C5–Trp» associates after PDDA addition in the ternary complex is achieved. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
|
ru_RU |
| dc.title |
Supramolecular nanoscale systems based on amphiphilic tetramethylensulfonatocalix[4]resorcinarenes and cationic polyelectrolyte with controlled guest molecule binding |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
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