| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2012 |
| Язык | английский |
|
Коновалов Александр Иванович, автор
Морозова Юлия Эрнестовна, автор
Шалаева Яна Викторовна, автор
|
|
Казакова Элла Хатибовна, автор
Латыпов Шамиль Камильевич, автор
Сякаев Виктор Васильевич, автор
|
| Библиографическое описание на языке оригинала |
Syakaev V. V. Guest controlled aggregation of amphiphilic sulfonatomethylated calix[4]resorcinarenes in aqueous solutions / V. V. Syakaev, E. Kh. Kazakova, J. E. Morozova, Ya. V. Shalaeva, Sh. K. Latypov, A. I. Konovalov // J. Colloid Interface Sci. - 2012. - V. 370. - P. 19-26 |
| Аннотация |
Supramolecular nanoaggregates formed through the association of amphiphilic sulfonatomethylated calix[4]resorcinarenes with different substituents on the lower rim and number of aromatic, aliphatic, and cationic guests differing in their shapes and sizes were investigated in aqueous solution by various NMR techniques. It was shown that slight variations of the alkyl chain length on the lower rim of calixresorcinarenes dramatically change their aggregation behavior. Unlike the other calixresorcinarenes studied, the ''head-to-tail'' packing mode is observed for calixresorcinarene with pentyl moieties on the lower rim, which is unusual for amphiphilic calixarene aggregates. This calixresorcinarene demonstrates the stronger binding capacity toward the guest molecules due to their encapsulation into the capsule-like aggregate subunits. |
| Ключевые слова |
Self-assembly, supramolecular, calixarene, hydrophobic effect, molecular capsules, NMR spectroscopy |
| Название журнала |
Journal of Colloid and Interface Science
|
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=139101 |
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Коновалов Александр Иванович |
ru_RU |
| dc.contributor.author |
Морозова Юлия Эрнестовна |
ru_RU |
| dc.contributor.author |
Шалаева Яна Викторовна |
ru_RU |
| dc.contributor.author |
Казакова Элла Хатибовна |
ru_RU |
| dc.contributor.author |
Латыпов Шамиль Камильевич |
ru_RU |
| dc.contributor.author |
Сякаев Виктор Васильевич |
ru_RU |
| dc.date.accessioned |
2012-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2012-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2012 |
ru_RU |
| dc.identifier.citation |
Syakaev V. V. Guest controlled aggregation of amphiphilic sulfonatomethylated calix[4]resorcinarenes in aqueous solutions / V. V. Syakaev, E. Kh. Kazakova, J. E. Morozova, Ya. V. Shalaeva, Sh. K. Latypov, A. I. Konovalov // J. Colloid Interface Sci. - 2012. - V. 370. - P. 19-26 |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=139101 |
ru_RU |
| dc.description.abstract |
Journal of Colloid and Interface Science |
ru_RU |
| dc.description.abstract |
Supramolecular nanoaggregates formed through the association of amphiphilic sulfonatomethylated calix[4]resorcinarenes with different substituents on the lower rim and number of aromatic, aliphatic, and cationic guests differing in their shapes and sizes were investigated in aqueous solution by various NMR techniques. It was shown that slight variations of the alkyl chain length on the lower rim of calixresorcinarenes dramatically change their aggregation behavior. Unlike the other calixresorcinarenes studied, the ''head-to-tail'' packing mode is observed for calixresorcinarene with pentyl moieties on the lower rim, which is unusual for amphiphilic calixarene aggregates. This calixresorcinarene demonstrates the stronger binding capacity toward the guest molecules due to their encapsulation into the capsule-like aggregate subunits. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
Self-assembly |
ru_RU |
| dc.subject |
supramolecular |
ru_RU |
| dc.subject |
calixarene |
ru_RU |
| dc.subject |
hydrophobic effect |
ru_RU |
| dc.subject |
molecular capsules |
ru_RU |
| dc.subject |
NMR spectroscopy |
ru_RU |
| dc.title |
Guest controlled aggregation of amphiphilic sulfonatomethylated calix[4]resorcinarenes in aqueous solutions |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
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