КФУ. Карточка публикации. Crystal violet dye in complexes with amphiphilic anionic calix[4]resorcinarenes: binding by aggregates and individual molecules

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CRYSTAL VIOLET DYE IN COMPLEXES WITH AMPHIPHILIC ANIONIC CALIX[4]RESORCINARENES: BINDING BY AGGREGATES AND INDIVIDUAL MOLECULES

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2013

Язык

английский

Авторы, сотрудники КФУ

Коновалов Александр Иванович, автор

Миронова Диана Александровна, автор

Морозова Юлия Эрнестовна, автор

Другие авторы

Казакова Элла Хатибовна, автор

Муслинкина Лия Абдурахимовна, автор

Сякаев Виктор Васильевич, автор

Янилкин Виталий Васильевич, автор

Библиографическое описание на языке оригинала

Mironova D.A. Crystal violet dye in complexes with amphiphilic anionic calix[4]resorcinarenes: binding by aggregates and individual molecules / D.A. Mironova, L. A. Muslinkina, V. V. Syakaev, J. E. Morozova, V. V. Yanilkin, A. I. Konovalov, E. Kh. Kazakova // J. Colloid Interf. Sci. - 2013. - V 407. - P. 148-154.

Аннотация

Here, we report on a systematic study of six calix[4]resorcinarene macrocycles bearing eight carboxylic groups on the upper rim and four different lower rim substituents that are either aliphatic (2, 4, and 5) or alkylaromatic (1, 3, and 6). The macrocycles were studied in their individual aqueous solutions and in the presence of triphenylmethane dye crystal violet. It was found that binding of crystal violet with aggregated macrocycles shields it from the bulk of solution, preventing its discoloration under basic conditions and electrochemical reduction on the glassy carbon electrode. Most efficient shielding, reducing the rate of discoloration more than 173 times, as compared to solution with no macrocycle, was achieved with 6 forming aggregates of average 72 molecules in 0.1 mM solutions.

Ключевые слова

Macrocycle, calix[4]resorcinarene, triphenylmethane dye, crystal violet, aggregation, NMR spectroscopy, UV?Vis, electrochemical reduction, fluorescence

Название журнала

Journal of Colloid and Interface Science

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https://repository.kpfu.ru/?p_id=139182

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Коновалов Александр Иванович	ru_RU
dc.contributor.author	Миронова Диана Александровна	ru_RU
dc.contributor.author	Морозова Юлия Эрнестовна	ru_RU
dc.contributor.author	Казакова Элла Хатибовна	ru_RU
dc.contributor.author	Муслинкина Лия Абдурахимовна	ru_RU
dc.contributor.author	Сякаев Виктор Васильевич	ru_RU
dc.contributor.author	Янилкин Виталий Васильевич	ru_RU
dc.date.accessioned	2013-01-01T00:00:00Z	ru_RU
dc.date.available	2013-01-01T00:00:00Z	ru_RU
dc.date.issued	2013	ru_RU
dc.identifier.citation	Mironova D.A. Crystal violet dye in complexes with amphiphilic anionic calix[4]resorcinarenes: binding by aggregates and individual molecules / D.A. Mironova, L. A. Muslinkina, V. V. Syakaev, J. E. Morozova, V. V. Yanilkin, A. I. Konovalov, E. Kh. Kazakova // J. Colloid Interf. Sci. - 2013. - V 407. - P. 148-154.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=139182	ru_RU
dc.description.abstract	Journal of Colloid and Interface Science	ru_RU
dc.description.abstract	Here, we report on a systematic study of six calix[4]resorcinarene macrocycles bearing eight carboxylic groups on the upper rim and four different lower rim substituents that are either aliphatic (2, 4, and 5) or alkylaromatic (1, 3, and 6). The macrocycles were studied in their individual aqueous solutions and in the presence of triphenylmethane dye crystal violet. It was found that binding of crystal violet with aggregated macrocycles shields it from the bulk of solution, preventing its discoloration under basic conditions and electrochemical reduction on the glassy carbon electrode. Most efficient shielding, reducing the rate of discoloration more than 173 times, as compared to solution with no macrocycle, was achieved with 6 forming aggregates of average 72 molecules in 0.1 mM solutions.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Macrocycle	ru_RU
dc.subject	calix[4]resorcinarene	ru_RU
dc.subject	triphenylmethane dye	ru_RU
dc.subject	crystal violet	ru_RU
dc.subject	aggregation	ru_RU
dc.subject	NMR spectroscopy	ru_RU
dc.subject	UV?Vis	ru_RU
dc.subject	electrochemical reduction	ru_RU
dc.subject	fluorescence	ru_RU
dc.title	Crystal violet dye in complexes with amphiphilic anionic calix[4]resorcinarenes: binding by aggregates and individual molecules	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU