Форма представления | Статьи в зарубежных журналах и сборниках |
Год публикации | 2017 |
Язык | английский |
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Осин Юрий Николаевич, автор
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Fazleeva R. R., автор
Gubaidullin A T, автор
Nasretdinova G R., автор
Yanilkin V. V., автор
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Библиографическое описание на языке оригинала |
G. R. Nasretdinova Methylviologen-Mediated Electrochemical Synthesis of Silver Nanoparticles via the Reduction of AgCl Nanospheres Stabilized by Cetyltrimethylammonium Chloride / G. R. Nasretdinova, R. R. Fazleeva, Yu. N. Osin, A. T. Gubaidullin, and V. V. Yanilkin // Russian Journal of Electrochemistry, 2017, Vol. 53, No. 1, pp. 25–38. |
Аннотация |
Russian Journal of Electrochemistry |
Ключевые слова |
electrosynthesis, nanoparticles, nanosphere, nanorod, silver, reduction, silver chloride, mediator, methylviologen, stabilizer, cetyltrimethylammonium chloride |
Название журнала |
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
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https://repository.kpfu.ru/?p_id=151755 |
Файлы ресурса | |
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Полная запись метаданных |
Поле DC |
Значение |
Язык |
dc.contributor.author |
Осин Юрий Николаевич |
ru_RU |
dc.contributor.author |
Fazleeva R. R. |
ru_RU |
dc.contributor.author |
Gubaidullin A T |
ru_RU |
dc.contributor.author |
Nasretdinova G R. |
ru_RU |
dc.contributor.author |
Yanilkin V. V. |
ru_RU |
dc.date.accessioned |
2017-01-01T00:00:00Z |
ru_RU |
dc.date.available |
2017-01-01T00:00:00Z |
ru_RU |
dc.date.issued |
2017 |
ru_RU |
dc.identifier.citation |
G. R. Nasretdinova Methylviologen-Mediated Electrochemical Synthesis of Silver Nanoparticles via the Reduction of AgCl Nanospheres Stabilized by Cetyltrimethylammonium Chloride / G. R. Nasretdinova, R. R. Fazleeva, Yu. N. Osin, A. T. Gubaidullin, and V. V. Yanilkin // Russian Journal of Electrochemistry, 2017, Vol. 53, No. 1, pp. 25–38. |
ru_RU |
dc.identifier.uri |
https://repository.kpfu.ru/?p_id=151755 |
ru_RU |
dc.description.abstract |
RUSSIAN JOURNAL OF ELECTROCHEMISTRY |
ru_RU |
dc.description.abstract |
Russian Journal of Electrochemistry |
ru_RU |
dc.description.abstract |
Abstract—Efficient synthesis of silver nanoparticles stabilized by cetyltrimethylammonium cations (Ag@CTA+) is carried out in aqueous medium by methylviologen-mediated electroreduction of silver chloride nanospheres stabilized by surface-active CTA+ cations (AgCl@CTA+, diameter ~330 nm), on a glassy carbon electrode at potentials of the MV2+/MV?+ redox couple. The nanospheres AgCl@CTA+ can be reduced immediately on the electrode at a low rate and the resulting metal is deposited on the electrode. In the mediated reduction, the metal is not deposited on the cathode but the quantitative reduction of AgCl to Ag@CTA+ nanoparticles proceeds completely in solution volume at the theoretical charge. In aqueous solution, the nanoparticles are positively charged (electrokinetic (zeta) potential is +74.6 mV), their characteristic absorption maximum is at 423 nm and the average hydrodynamic diameter is 77 nm. Isolated Ag@CTACl nanoparticles have the size of 39 ? 15 nm. |
ru_RU |
dc.language.iso |
ru |
ru_RU |
dc.subject |
electrosynthesis |
ru_RU |
dc.subject |
nanoparticles |
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dc.subject |
nanosphere |
ru_RU |
dc.subject |
nanorod |
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dc.subject |
silver |
ru_RU |
dc.subject |
reduction |
ru_RU |
dc.subject |
silver chloride |
ru_RU |
dc.subject |
mediator |
ru_RU |
dc.subject |
methylviologen |
ru_RU |
dc.subject |
stabilizer |
ru_RU |
dc.subject |
cetyltrimethylammonium chloride |
ru_RU |
dc.title |
Methylviologen-Mediated Electrochemical Synthesis of Silver Nanoparticles via the Reduction of AgCl Nanospheres Stabilized by Cetyltrimethylammonium Chloride |
ru_RU |
dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
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