Казанский (Приволжский) федеральный университет, КФУ
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ELECTROCHEMICAL SYNTHESIS AND PROPERTIES OF ORGANONICKEL σ‑COMPLEXES
Форма представленияСтатьи в зарубежных журналах и сборниках
Год публикации2014
Языкрусский
  • Хуснуриялова Алия Фанусовна, автор
  • Яхваров Дмитрий Григорьевич, автор
  • Хуснуриялова Алия Фанусовна, автор
  • Библиографическое описание на языке оригинала D.G.Yakhvarov, A.F.Khusnuriyalova, O.G.Sinyashin. Electrochemical Synthesis and Properties of Organonickel σ-Complexes. Organometallics. 2014, 33, 4574-4589.
    Аннотация The organonickel complexes are organometallic compounds containing a Ni−C σ-bond (σ-complexes). These species are very reactive and have been mainly characterized as the intermediates of catalytic processes of cross coupling and homocoupling involving organic and elementoorganic substrates such as organic halides, chlorophosphines, unsaturated hydrocarbons, etc. Thus, only a limited number of these complexes have been isolated and characterized as the free stable species. Although the organonickel complexes have been known since the 1960s, the chemistry of these species is currently at the beginning stages of development. The interest of the researchers in this class of compounds has significantly increased over the past decade, resulting in a plethora of scientific papers published on this topic. At the same time, electrochemical methods have become more and more popular in modern synthetic chemistry, due to easy access to high reactive intermediates, including organometallic species,
    Ключевые слова Organonickel sigma-complexes, electrochemistry, electrochemical synthesis, oligomerization, ethylene
    Название журнала Organometallics
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