КФУ. Карточка публикации. Molecular recognition of nitrogen–containing bases by Zn[5,15-bis-(2,6-dodecyloxyphenyl)]porphyrin

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MOLECULAR RECOGNITION OF NITROGEN&NDASH;CONTAINING BASES BY ZN[5,15-BIS-(2,6-DODECYLOXYPHENYL)]PORPHYRIN

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2017

Язык

английский

Авторы, сотрудники КФУ

Ходов Илья Анатольевич, автор

Библиографическое описание на языке оригинала

Maltceva O, Mamardashvili G, Khodov I, Molecular recognition of nitrogen–containing bases by Zn[5,15-bis-(2,6-dodecyloxyphenyl)]porphyrin //Supramolecular Chemistry. - 2017. - Vol.29, Is.5. - P.360-369.

Аннотация

Supramolecular Chemistry

Ключевые слова

NMR, 2D NMR, DOSY, binding ability, Porphyrin receptor, sensing device, spectrophotometric titration.

Название журнала

Supramolecular Chemistry

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-84990973232&partnerID=40&md5=83375a4c18f1ba08934ef7fca1786c62

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https://repository.kpfu.ru/?p_id=159265

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Ходов Илья Анатольевич	ru_RU
dc.date.accessioned	2017-01-01T00:00:00Z	ru_RU
dc.date.available	2017-01-01T00:00:00Z	ru_RU
dc.date.issued	2017	ru_RU
dc.identifier.citation	Maltceva O, Mamardashvili G, Khodov I, Molecular recognition of nitrogen–containing bases by Zn[5,15-bis-(2,6-dodecyloxyphenyl)]porphyrin //Supramolecular Chemistry. - 2017. - Vol.29, Is.5. - P.360-369.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=159265	ru_RU
dc.description.abstract	Supramolecular Chemistry	ru_RU
dc.description.abstract	Supramolecular Chemistry	ru_RU
dc.description.abstract	By means of spectrophotometric titration and 1H NMR spectroscopy, the selective binding ability of the Zn-5,15-bis-(2,6-dodecyloxyphenyl)porphyrin towards nitrogen containing organic molecules of various nature has been studied. It has been found that the presence of long alkoxy substituents at the ortho-positions of the Zn-porphyrin phenyl rings prevents the axial coordination of tertiary amines and, conversely, creates favourable conditions for binding of a primary diamine due to the presence of additional binding sites, namely the oxygen atoms of the ortho–ortho'- dodecyloxy substituents of the meso phenyl groups. The formation of stable complexes with multiple binding sites has been confirmed by DFT quantum chemical calculations and two-dimensional NMR experiments.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	NMR	ru_RU
dc.subject	2D NMR	ru_RU
dc.subject	DOSY	ru_RU
dc.subject	binding ability	ru_RU
dc.subject	Porphyrin receptor	ru_RU
dc.subject	sensing device	ru_RU
dc.subject	spectrophotometric titration.	ru_RU
dc.title	Molecular recognition of nitrogen–containing bases by Zn[5,15-bis-(2,6-dodecyloxyphenyl)]porphyrin	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU