| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2017 |
| Язык | английский |
|
Ходов Илья Анатольевич, автор
|
| Библиографическое описание на языке оригинала |
Ksenofontov A.A, Guseva G.B, Antinр E.V, Zinc(II) bis(dipyrromethenate)s crystal solvates with dimethyl sulfoxide Composition, stability and spectral-luminescent properties//Sensors and Actuators, B: Chemical. - 2017. - Vol.251, Is.. - P.858-868. |
| Аннотация |
This paper presents the results of UV/vis, fluorescence, FT-IR, DOSY, and DFT study of a novel non-covalent supramolecular systems based on zinc(II) bis(dipyrromethenate)s ([Zn2L2]) with C60. It was found that zinc(II) bis(dipyrromethenate) forms stable supramolecular π-π-complexes ([Zn2L2(C60)4]) with C60. DFT calculations revealed stable complexation between [Zn2L2] and C60. The [Zn2L2(C60)4] LUMO energy levels are predominantly spread on the C60 unit and the HOMO energy levels are mainly spread on the [Zn2L2]. The photoinduced electron transfer testing by the substantial fluorescence quenching of the [Zn2L2] by non-covalent bonded C60 gives the positive result that shows prospects of the studying [Zn2L2(C60)4] as the active layers in solar energy conversion devices. 2018 Elsevier B.V. |
| Ключевые слова |
NMR, DOSY, Fluorescence, Fullerenes, Non-covalent, Supramolecular systems, Zinc(II) bis(dipyrromethenate)s. |
| Название журнала |
Sensors and Actuators, B: Chemical
|
| URL |
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85020047247&doi=10.1016%2fj.snb.2017.05.143&partnerID=40&md5=66d6bdc569b6e129750f4c01d77fe134 |
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=161672 |
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Ходов Илья Анатольевич |
ru_RU |
| dc.date.accessioned |
2017-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2017-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2017 |
ru_RU |
| dc.identifier.citation |
Ksenofontov A.A, Guseva G.B, Antinр E.V, Zinc(II) bis(dipyrromethenate)s crystal solvates with dimethyl sulfoxide Composition, stability and spectral-luminescent properties//Sensors and Actuators, B: Chemical. - 2017. - Vol.251, Is.. - P.858-868. |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=161672 |
ru_RU |
| dc.description.abstract |
Sensors and Actuators, B: Chemical |
ru_RU |
| dc.description.abstract |
This paper presents the results of UV/vis, fluorescence, FT-IR, DOSY, and DFT study of a novel non-covalent supramolecular systems based on zinc(II) bis(dipyrromethenate)s ([Zn2L2]) with C60. It was found that zinc(II) bis(dipyrromethenate) forms stable supramolecular π-π-complexes ([Zn2L2(C60)4]) with C60. DFT calculations revealed stable complexation between [Zn2L2] and C60. The [Zn2L2(C60)4] LUMO energy levels are predominantly spread on the C60 unit and the HOMO energy levels are mainly spread on the [Zn2L2]. The photoinduced electron transfer testing by the substantial fluorescence quenching of the [Zn2L2] by non-covalent bonded C60 gives the positive result that shows prospects of the studying [Zn2L2(C60)4] as the active layers in solar energy conversion devices. 2018 Elsevier B.V. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
NMR |
ru_RU |
| dc.subject |
DOSY |
ru_RU |
| dc.subject |
Fluorescence |
ru_RU |
| dc.subject |
Fullerenes |
ru_RU |
| dc.subject |
Non-covalent |
ru_RU |
| dc.subject |
Supramolecular systems |
ru_RU |
| dc.subject |
Zinc(II) bis(dipyrromethenate)s. |
ru_RU |
| dc.title |
Zinc(II) bis(dipyrromethenate)s crystal solvates with dimethyl sulfoxide Composition, stability and spectral-luminescent properties |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
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