| Форма представления | Статьи в российских журналах и сборниках |
| Год публикации | 2013 |
| Язык | английский |
|
Гнездилов Олег Иванович, автор
|
| Библиографическое описание на языке оригинала |
Suleimanov, N.M. In sity muSR and NMR investigation of methanol dissociation on carbon-supported nanoscaled Pt-Ru catalyst/ N.M. Suleimanov, S.M. Khantimerov, R. Scheuermann, D. Herlach, A.A. Loschin, O.I. Gnezdilov, Yu.A. Sakhratov, V.L. Matukhin // J. Solid. State Electrochem. – 2013. –V.17. - P.2115-2122. |
| Аннотация |
In situ muSR and nuclear magnetic resonance
(NMR) experiments on the investigation of methanol
decomposition on Pt-Ru nanoscaled catalyst supported on
Vulcan XC-72 carbon black (Pt-Ru/Vulcan XC-72) are
presented. Avoided-level-crossing muon spin resonance
measurements reveal the resonance line at magnetic field
2.018 T, we assign to transient CH2OMu? formaldehyde
muonated radical. Results obtained allow us to estimate the
contribution of chemical decomposition reaction process
for the formaldehyde—carbon oxide—hydrogen conversion
on Pt-Ru/Vulcan XC-72 catalytic material. NMR
spectrum of the methanol covered Pt-Ru/Vulcan XC-72
consists of three broad resonance lines. Two of them are
assigned to OH and CH3 groups of methanol bound to the
carbon black surface. Following the existing literature,
which indicates that polymerization of formaldehyde
readily takes place when the monomer is adsorbed on
some active surface, the third one is assigned to the
resonance signal of oligomeric species |
| Ключевые слова |
Methanol decomposition, intermediate reaction
products, carbon-supported catalysts, MuSR, NMR |
| Название журнала |
Journal of Solid State Electrochemistry
|
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=163230 |
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Гнездилов Олег Иванович |
ru_RU |
| dc.date.accessioned |
2013-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2013-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2013 |
ru_RU |
| dc.identifier.citation |
Suleimanov, N.M. In sity muSR and NMR investigation of methanol dissociation on carbon-supported nanoscaled Pt-Ru catalyst/ N.M. Suleimanov, S.M. Khantimerov, R. Scheuermann, D. Herlach, A.A. Loschin, O.I. Gnezdilov, Yu.A. Sakhratov, V.L. Matukhin // J. Solid. State Electrochem. – 2013. –V.17. - P.2115-2122. |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=163230 |
ru_RU |
| dc.description.abstract |
Journal of Solid State Electrochemistry |
ru_RU |
| dc.description.abstract |
In situ muSR and nuclear magnetic resonance
(NMR) experiments on the investigation of methanol
decomposition on Pt-Ru nanoscaled catalyst supported on
Vulcan XC-72 carbon black (Pt-Ru/Vulcan XC-72) are
presented. Avoided-level-crossing muon spin resonance
measurements reveal the resonance line at magnetic field
2.018 T, we assign to transient CH2OMu? formaldehyde
muonated radical. Results obtained allow us to estimate the
contribution of chemical decomposition reaction process
for the formaldehyde—carbon oxide—hydrogen conversion
on Pt-Ru/Vulcan XC-72 catalytic material. NMR
spectrum of the methanol covered Pt-Ru/Vulcan XC-72
consists of three broad resonance lines. Two of them are
assigned to OH and CH3 groups of methanol bound to the
carbon black surface. Following the existing literature,
which indicates that polymerization of formaldehyde
readily takes place when the monomer is adsorbed on
some active surface, the third one is assigned to the
resonance signal of oligomeric species |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
Methanol decomposition |
ru_RU |
| dc.subject |
intermediate reaction
products |
ru_RU |
| dc.subject |
carbon-supported catalysts |
ru_RU |
| dc.subject |
MuSR |
ru_RU |
| dc.subject |
NMR |
ru_RU |
| dc.title |
In sity muSR and NMR investigation of methanol dissociation on carbon-supported nanoscaled Pt-Ru catalyst |
ru_RU |
| dc.type |
Статьи в российских журналах и сборниках |
ru_RU |
|
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