| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2018 |
| Язык | английский |
|
Сухов Александр Вячеславович, автор
Хуснуриялова Алия Фанусовна, автор
|
| Библиографическое описание на языке оригинала |
Aliya F. Khusnuriyalova, Andreas Petr, Aidar T. Gubaidullin, Aleksandr V. Sukhov, Vladimir I. Morozov, Bernd Büchner, Vladislav Kataev, Oleg G. Sinyashin, Dmitry G. Yakhvarov. Electrochemical generation and observation by magnetic resonance of superparamagnetic cobalt nanoparticles. Electrochimica Acta. 2018, 260, 324-329. |
| Аннотация |
The electrochemical reduction of cobalt dibromide 2,20-bipyridine (bpy) complexes (Co/bpy molar ratio
1:1) results in the formation of cobalt nanoparticles (CoNP) formed by the disproportionation reaction of
the electrochemically generated cobalt(I) mononuclear complexes. The process of the electrochemical
generation of CoNP was monitored by in situ EPR-spectroelectrochemistry where the signals of the
ferromagnetic resonance (FMR) have been observed for these species. According to small-angle X-ray
scattering (SAXS) analysis the average diameter and the average length of the formed cylindrical CoNP is
varied from 9 to 10 nm and 30e32 nm, respectively, and correlates to the g-value and the broadness of
the FMR signal observed by in situ EPR-spectroelectrochemistry during electrochemical process. |
| Ключевые слова |
2,2'-bipyridine, cobalt complexes, cobalt nanoparticles, electrochemistry, in situ EPR spectroelectrochemistry |
| Название журнала |
ELECTROCHIMICA ACTA
|
| URL |
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85038114421&doi=10.1016%2fj.electacta.2017.12.050&partnerID=40&md5=98673d414e5202b204fc46c1d1c8dc07 |
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=174436 |
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Сухов Александр Вячеславович |
ru_RU |
| dc.contributor.author |
Хуснуриялова Алия Фанусовна |
ru_RU |
| dc.date.accessioned |
2018-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2018-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2018 |
ru_RU |
| dc.identifier.citation |
Aliya F. Khusnuriyalova, Andreas Petr, Aidar T. Gubaidullin, Aleksandr V. Sukhov, Vladimir I. Morozov, Bernd Büchner, Vladislav Kataev, Oleg G. Sinyashin, Dmitry G. Yakhvarov. Electrochemical generation and observation by magnetic resonance of superparamagnetic cobalt nanoparticles. Electrochimica Acta. 2018, 260, 324-329. |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=174436 |
ru_RU |
| dc.description.abstract |
ELECTROCHIMICA ACTA |
ru_RU |
| dc.description.abstract |
The electrochemical reduction of cobalt dibromide 2,20-bipyridine (bpy) complexes (Co/bpy molar ratio
1:1) results in the formation of cobalt nanoparticles (CoNP) formed by the disproportionation reaction of
the electrochemically generated cobalt(I) mononuclear complexes. The process of the electrochemical
generation of CoNP was monitored by in situ EPR-spectroelectrochemistry where the signals of the
ferromagnetic resonance (FMR) have been observed for these species. According to small-angle X-ray
scattering (SAXS) analysis the average diameter and the average length of the formed cylindrical CoNP is
varied from 9 to 10 nm and 30e32 nm, respectively, and correlates to the g-value and the broadness of
the FMR signal observed by in situ EPR-spectroelectrochemistry during electrochemical process. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
2 |
ru_RU |
| dc.subject |
2'-bipyridine |
ru_RU |
| dc.subject |
cobalt complexes |
ru_RU |
| dc.subject |
cobalt nanoparticles |
ru_RU |
| dc.subject |
electrochemistry |
ru_RU |
| dc.subject |
in situ EPR spectroelectrochemistry |
ru_RU |
| dc.title |
Electrochemical generation and observation by magnetic resonance of superparamagnetic cobalt nanoparticles |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
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