| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2018 |
| Язык | английский |
|
Курбангалиева Альмира Рафаэловна, автор
Лодочникова Ольга Александровна, автор
Потапова Любовь Николаевна, автор
|
|
Зарипова Айгуль Рамильевна, автор
|
| Библиографическое описание на языке оригинала |
Lodochnikova О. А. «Doubly enantiophobic» behavior during crystallization of racemic 1,5-dihydro-2H-pyrrol-2-one thioether / O. A. Lodochnikova, A. R. Zaripova, R. R. Fayzullin, A. I. Samigullina, I. I. Vandyukova, L. N. Potapova, A. R. Kurbangalieva // CrystEngComm. – 2018. – V. 20, № 23. – P. 3218–3227. |
| Аннотация |
The titled compound 7 demonstrates unusual «doubly enantiophobic« behavior during crystallization. Namely, the mentioned substance forms two polymorphic modifications 7a and 7b that appear to be racemic conglomerates in the space groups P21 and P65 (or P61), respectively. Both 7a and 7b are thermodynamically stable at certain temperature ranges. Hence, γ-lactam 7 is prone to spontaneous resolution of the racemate into the enantiomers in two different ways, which is an exceptional phenomenon. Phase behavior and structure of the crystalline modifications of 7 were investigated by means of single crystal and
powder X-ray diffraction, differential scanning calorimetry, temperature-resolved vibration spectroscopy, and hot-stage microscopy. |
| Ключевые слова |
3-Pyrrolin-2-one, conglomerate, spontaneous resolution |
| Название журнала |
CRYSTENGCOMM
|
| URL |
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85048447909&doi=10.1039%2fc8ce00369f&partnerID=40&md5=8debfa970609aaed4f16fe3ae0f61034 |
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=183293 |
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Курбангалиева Альмира Рафаэловна |
ru_RU |
| dc.contributor.author |
Лодочникова Ольга Александровна |
ru_RU |
| dc.contributor.author |
Потапова Любовь Николаевна |
ru_RU |
| dc.contributor.author |
Зарипова Айгуль Рамильевна |
ru_RU |
| dc.date.accessioned |
2018-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2018-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2018 |
ru_RU |
| dc.identifier.citation |
Lodochnikova О. А. «Doubly enantiophobic» behavior during crystallization of racemic 1,5-dihydro-2H-pyrrol-2-one thioether / O. A. Lodochnikova, A. R. Zaripova, R. R. Fayzullin, A. I. Samigullina, I. I. Vandyukova, L. N. Potapova, A. R. Kurbangalieva // CrystEngComm. – 2018. – V. 20, № 23. – P. 3218–3227. |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=183293 |
ru_RU |
| dc.description.abstract |
CRYSTENGCOMM |
ru_RU |
| dc.description.abstract |
The titled compound 7 demonstrates unusual «doubly enantiophobic« behavior during crystallization. Namely, the mentioned substance forms two polymorphic modifications 7a and 7b that appear to be racemic conglomerates in the space groups P21 and P65 (or P61), respectively. Both 7a and 7b are thermodynamically stable at certain temperature ranges. Hence, γ-lactam 7 is prone to spontaneous resolution of the racemate into the enantiomers in two different ways, which is an exceptional phenomenon. Phase behavior and structure of the crystalline modifications of 7 were investigated by means of single crystal and
powder X-ray diffraction, differential scanning calorimetry, temperature-resolved vibration spectroscopy, and hot-stage microscopy. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
3-Pyrrolin-2-one |
ru_RU |
| dc.subject |
conglomerate |
ru_RU |
| dc.subject |
spontaneous resolution |
ru_RU |
| dc.title |
«Doubly enantiophobic» behavior during crystallization of racemic 1,5-dihydro-2H-pyrrol-2-one thioether |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
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