| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2018 |
| Язык | английский |
|
Амиров Рустэм Рафаэльевич, автор
Неклюдов Вадим Вячеславович, автор
Чмутова Галина Алексеевна, автор
|
|
Шулаева Марина Михайловна, автор
|
|
Багина Юлия Игоревна, автор
|
| Библиографическое описание на языке оригинала |
Neklyudov, V.V. Complex Formation of 1,5-Bis(amidomethylsulfonyl)pentane with Copper(II) and Iron(III) / V.V. Neklyudov, G.A. Boos, G.A. Chmutova, M.M. Shulaeva, Y.I. Bagina, R.R. Amirov // Russian Journal of General Chemistry. - 2018. - Volume 88, Issue 8. P. 1672-1680.
|
| Аннотация |
The state of the new antitubercular agent 1,5-bis(amidomethylsulfonyl)pentane in aqueous micellar solution of the nonionic surfactant Bridge 35 and its complexing properties toward copper(II) and iron(III) ions have been studied by spectrophotometry, pH potentiometry (25?C, variable ionic strength), and mathematical modeling. In the concentration range from 5.00 × 10–5 to 1.00 × 10–3 M in the presence of Bridge 35, the title compound exists in a neutral monomeric form. It forms 1: 2 mononuclear and 2: 2 binuclear complexes with copper(II) and 1: 1 and 1: 2 mononuclear and 2: 1 binuclear complexes with iron(III). The most favorable structures of 1,5-bis(amidomethylsulfonyl)pentane and its complexes have been simulated in terms of the density functional theory. |
| Ключевые слова |
The state of the new antitubercular agent 1,5-bis(amidomethylsulfonyl)pentane in aqueous micellar solution of the nonionic surfactant Bridge 35 and its complexing properties toward copper(II) and iron(III) ions have been studied by spectrophotometry, pH potentiometry (25?C, variable ionic strength), and mathematical modeling. In the concentration range from 5.00 × 10?5 to 1.00 × 10?3 M in the presence of Bridge 35, the title compound exists in a neutral monomeric form. It forms 1: 2 mononuclear and 2: 2 binuclear complexes with copper(II) and 1: 1 and 1: 2 mononuclear and 2: 1 binuclear complexes with iron(III). The most favorable structures of 1,5-bis(amidomethylsulfonyl)pentane and its complexes have been simulated in terms of the density functional theory. |
| Название журнала |
Russian Journal of General Chemistry
|
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=190369 |
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Амиров Рустэм Рафаэльевич |
ru_RU |
| dc.contributor.author |
Неклюдов Вадим Вячеславович |
ru_RU |
| dc.contributor.author |
Чмутова Галина Алексеевна |
ru_RU |
| dc.contributor.author |
Шулаева Марина Михайловна |
ru_RU |
| dc.contributor.author |
Багина Юлия Игоревна |
ru_RU |
| dc.date.accessioned |
2018-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2018-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2018 |
ru_RU |
| dc.identifier.citation |
Neklyudov, V.V. Complex Formation of 1,5-Bis(amidomethylsulfonyl)pentane with Copper(II) and Iron(III) / V.V. Neklyudov, G.A. Boos, G.A. Chmutova, M.M. Shulaeva, Y.I. Bagina, R.R. Amirov // Russian Journal of General Chemistry. - 2018. - Volume 88, Issue 8. P. 1672-1680.
|
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=190369 |
ru_RU |
| dc.description.abstract |
Russian Journal of General Chemistry |
ru_RU |
| dc.description.abstract |
The state of the new antitubercular agent 1,5-bis(amidomethylsulfonyl)pentane in aqueous micellar solution of the nonionic surfactant Bridge 35 and its complexing properties toward copper(II) and iron(III) ions have been studied by spectrophotometry, pH potentiometry (25?C, variable ionic strength), and mathematical modeling. In the concentration range from 5.00 × 10–5 to 1.00 × 10–3 M in the presence of Bridge 35, the title compound exists in a neutral monomeric form. It forms 1: 2 mononuclear and 2: 2 binuclear complexes with copper(II) and 1: 1 and 1: 2 mononuclear and 2: 1 binuclear complexes with iron(III). The most favorable structures of 1,5-bis(amidomethylsulfonyl)pentane and its complexes have been simulated in terms of the density functional theory. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
The state of the new antitubercular agent 1 |
ru_RU |
| dc.subject |
5-bis(amidomethylsulfonyl)pentane in aqueous micellar solution of the nonionic surfactant Bridge 35 and its complexing properties toward copper(II) and iron(III) ions have been studied by spectrophotometry |
ru_RU |
| dc.subject |
pH potentiometry (25?C |
ru_RU |
| dc.subject |
variable ionic strength) |
ru_RU |
| dc.subject |
and mathematical modeling. In the concentration range from 5.00 × 10?5 to 1.00 × 10?3 M in the presence of Bridge 35 |
ru_RU |
| dc.subject |
the title compound exists in a neutral monomeric form. It forms 1: 2 mononuclear and 2: 2 binuclear complexes with copper(II) and 1: 1 and 1: 2 mononuclear and 2: 1 binuclear complexes with iron(III). The most favorable structures of 1 |
ru_RU |
| dc.subject |
5-bis(amidomethylsulfonyl)pentane and its complexes have been simulated in terms of the density functional theory. |
ru_RU |
| dc.title |
Complex Formation of 1,5-Bis(amidomethylsulfonyl)pentane with Copper(II) and Iron(III)(Article)
|
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
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