Казанский (Приволжский) федеральный университет, КФУ
КАЗАНСКИЙ
ФЕДЕРАЛЬНЫЙ УНИВЕРСИТЕТ
 
POLYMER DEGRADATION AND STABILITY
Форма представленияСтатьи в зарубежных журналах и сборниках
Год публикации2018
  • Варфоломеев Михаил Алексеевич, автор
  • Фархадиан Абдолреза , автор
  • Фархадиан Абдолреза , автор
  • Библиографическое описание на языке оригинала The purpose of this study is to synthesize non-isocyanate poly (ester amide/urethane) networks, based entirely on vegetable oil through a green method, i.e., without solvent and having any rigid and aromatic structures to improve their thermal stability. For this purpose, first, three amines were synthesized from castor oil and oleic acid. Second, carbonated sunflower oil (CSFO) was obtained by reaction of epoxidized sunflower oil with CO2 at atmospheric pressure. In the final step, CSFO easily reacted with bio-based amines by melt-blending without catalyst to give corresponding non-isocyanate polyurethane (NIPU) networks. The Fourier-transform infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR), X-ray powder diffraction (XRD), differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA) and thermogravimetric analysis (TGA) techniques were applied to characterize the structural, thermal and physical features of NIPU networks. In addition, to determine the envir
    Аннотация Polymer Degradation and Stability
    Ключевые слова Non-isocyanate poly (ester amide/urethane) network Vegetable oils Biobased polymers Environment-friendly synthesis Thermal stability Green chemistry
    Название журнала Polymer Degradation and Stability
    Издательство Elsevier
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