| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2018 |
| Язык | английский |
|
Лисицын Юрий Анатольевич, автор
Сухов Александр Вячеславович, автор
|
| Библиографическое описание на языке оригинала |
Lisitsyn Y.A, Sukhov A.V., Electrochemical Amination of Chlorobenzene in Aqueous-Organic Solutions of Sulfuric Acid//Russian Journal of Electrochemistry. - 2018. - Vol.54, Is.11. - P.886-892. |
| Аннотация |
The process of electrochemical amination of chlorobenzene using hydroxylamine and the
Ti(IV)/Ti(III) mediator system is studied in aqueous solutions of 6–16 M sulfuric acid containing acetic acid
or acetonitrile. The substitution products in these media are isomeric chloroanilines and chlorophenylenediamines,
with the exception of 5-chloro-1,3-isomer, phenylenediamines, and aniline. The overall current efficiency
of amino compounds corresponding under the experimental conditions to the efficiency by hydroxylamine
can reach 71%. Para- and ortho-chloroanilines are obtained in 6 M sulfuric acid and 11.1 M acetic acid
with the weight fraction and current efficiency of 97 and 51%, respectively. |
| Ключевые слова |
cathode, Ti(IV)/Ti(III) mediator system, hydroxylamine, amino cation?radical, chlorobenzene,
cation?radical aromatic substitution, chloroanilines, chlorophenylenediamines |
| Название журнала |
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
|
| URL |
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85061324774&doi=10.1134%2fS1023193518130268&partnerID=40&md5=ca34cf8e805662b38d6377d1e194163d |
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=197921 |
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Лисицын Юрий Анатольевич |
ru_RU |
| dc.contributor.author |
Сухов Александр Вячеславович |
ru_RU |
| dc.date.accessioned |
2018-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2018-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2018 |
ru_RU |
| dc.identifier.citation |
Lisitsyn Y.A, Sukhov A.V., Electrochemical Amination of Chlorobenzene in Aqueous-Organic Solutions of Sulfuric Acid//Russian Journal of Electrochemistry. - 2018. - Vol.54, Is.11. - P.886-892. |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=197921 |
ru_RU |
| dc.description.abstract |
RUSSIAN JOURNAL OF ELECTROCHEMISTRY |
ru_RU |
| dc.description.abstract |
The process of electrochemical amination of chlorobenzene using hydroxylamine and the
Ti(IV)/Ti(III) mediator system is studied in aqueous solutions of 6–16 M sulfuric acid containing acetic acid
or acetonitrile. The substitution products in these media are isomeric chloroanilines and chlorophenylenediamines,
with the exception of 5-chloro-1,3-isomer, phenylenediamines, and aniline. The overall current efficiency
of amino compounds corresponding under the experimental conditions to the efficiency by hydroxylamine
can reach 71%. Para- and ortho-chloroanilines are obtained in 6 M sulfuric acid and 11.1 M acetic acid
with the weight fraction and current efficiency of 97 and 51%, respectively. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
cathode |
ru_RU |
| dc.subject |
Ti(IV)/Ti(III) mediator system |
ru_RU |
| dc.subject |
hydroxylamine |
ru_RU |
| dc.subject |
amino cation?radical |
ru_RU |
| dc.subject |
chlorobenzene |
ru_RU |
| dc.subject |
cation?radical aromatic substitution |
ru_RU |
| dc.subject |
chloroanilines |
ru_RU |
| dc.subject |
chlorophenylenediamines |
ru_RU |
| dc.title |
Electrochemical Amination of Chlorobenzene in Aqueous-Organic Solutions of Sulfuric Acid |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
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