| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2018 |
| Язык | английский |
|
Лисицын Юрий Анатольевич, автор
Сухов Александр Вячеславович, автор
|
| Библиографическое описание на языке оригинала |
Lisitsyn Y.A, Sukhov A.V., Electrochemical Amination. Selective Functionalization of para- and ortho-Anisidines in Aqueous Sulfuric Acid Solutions//Russian Journal of Electrochemistry. - 2018. - Vol.54, Is.12. - P.1294-1297. |
| Аннотация |
The processes of the electrochemical amination of para- and ortho-anisidines using hydroxylamine
and the Ti(IV)/Ti(III) mediator system are studied in aqueous solutions of 4–14 M sulfuric acid. The functionalization
of para-anisidine results in the formation of 4-methoxy-1,3- and 4-methoxy-1,2-phenylenediamines
with a current efficiency of up to 64.3 and 0.56%, respectively. When ortho-anisidine is aminated,
4-methoxy-1,3-phenylenediamine is the only substitution product; its current efficiency reaches 61%. Under
the conditions that favor synthesis of 4-methoxy-1,3-phenylenediamine from anisidines, full conversion of
hydroxylamine is observed and the current efficiency of the diamino compound corresponds to the yield per
amino radical source. |
| Ключевые слова |
cathode, Ti(IV)/Ti(III) mediator system, hydroxylamine, para-anisidine, ortho-anisidine,
4-methoxy-1,3-phenylenediamine |
| Название журнала |
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
|
| URL |
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85062298952&doi=10.1134%2fS102319351813027X&partnerID=40&md5=521f518924c50df21a9be33d714b31ee |
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=197922 |
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Лисицын Юрий Анатольевич |
ru_RU |
| dc.contributor.author |
Сухов Александр Вячеславович |
ru_RU |
| dc.date.accessioned |
2018-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2018-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2018 |
ru_RU |
| dc.identifier.citation |
Lisitsyn Y.A, Sukhov A.V., Electrochemical Amination. Selective Functionalization of para- and ortho-Anisidines in Aqueous Sulfuric Acid Solutions//Russian Journal of Electrochemistry. - 2018. - Vol.54, Is.12. - P.1294-1297. |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=197922 |
ru_RU |
| dc.description.abstract |
RUSSIAN JOURNAL OF ELECTROCHEMISTRY |
ru_RU |
| dc.description.abstract |
The processes of the electrochemical amination of para- and ortho-anisidines using hydroxylamine
and the Ti(IV)/Ti(III) mediator system are studied in aqueous solutions of 4–14 M sulfuric acid. The functionalization
of para-anisidine results in the formation of 4-methoxy-1,3- and 4-methoxy-1,2-phenylenediamines
with a current efficiency of up to 64.3 and 0.56%, respectively. When ortho-anisidine is aminated,
4-methoxy-1,3-phenylenediamine is the only substitution product; its current efficiency reaches 61%. Under
the conditions that favor synthesis of 4-methoxy-1,3-phenylenediamine from anisidines, full conversion of
hydroxylamine is observed and the current efficiency of the diamino compound corresponds to the yield per
amino radical source. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
cathode |
ru_RU |
| dc.subject |
Ti(IV)/Ti(III) mediator system |
ru_RU |
| dc.subject |
hydroxylamine |
ru_RU |
| dc.subject |
para-anisidine |
ru_RU |
| dc.subject |
ortho-anisidine |
ru_RU |
| dc.subject |
4-methoxy-1 |
ru_RU |
| dc.subject |
3-phenylenediamine |
ru_RU |
| dc.title |
Electrochemical Amination. Selective Functionalization of para- and ortho-Anisidines in Aqueous Sulfuric Acid Solutions |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
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