КФУ. Карточка публикации. Process of electrochemical electrode modification by polyaniline in the frame of percolation model

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PROCESS OF ELECTROCHEMICAL ELECTRODE MODIFICATION BY POLYANILINE IN THE FRAME OF PERCOLATION MODEL

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2019

Язык

английский

Авторы, сотрудники КФУ

Будников Герман Константинович, автор

Другие авторы

Нигматуллин Равиль Рашидович, автор

Сидельников Артем Владимирович, автор

Библиографическое описание на языке оригинала

Nigmatullin, R.R.Process of electrochemical electrode modification by polyaniline in the frame of percolation model/ Nigmatullin, R.R.Budnikov, H.C., Mustafin, A.G., Sidelnikov, A.V., Andriianova, A.N., Shigapova, A.R.//Journal of Solid State Electrochemistry (2019) 23:1221–1235

Аннотация

The polymer has wide application as chemical modifier of electrodes for voltammetry. Electrochemical polymerization of aniline includes in itself some oxidation/reduction stages of electroactive groups. In the result of this process, polyaniline structures of different contents are formed. The qualitative and quantitative contents of polymer film and its area and morphology during the polymerization process play an important role in electroconductivity and response of the final synthesis product on analyte.We demonstrate a possibility of quantitative description of the polyaniline electrochemical polymerization process in the frame of percolation model covering wide temporal range (100–500 reduction/oxidation cycles). We can evaluate the basic parameters (number of percolation channels and fractal dimensions with respect to the applied potential) characterizing the quality of electrode polymer cover. The microphotos obtained with the help of the high-resolution scanning electron microscope support the obtained results independently.

Ключевые слова

polyaniline,percolation model, voltammogram,fractal dimension

Название журнала

J SOLID STATE ELECTR

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https://repository.kpfu.ru/?p_id=199251

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Будников Герман Константинович	ru_RU
dc.contributor.author	Нигматуллин Равиль Рашидович	ru_RU
dc.contributor.author	Сидельников Артем Владимирович	ru_RU
dc.date.accessioned	2019-01-01T00:00:00Z	ru_RU
dc.date.available	2019-01-01T00:00:00Z	ru_RU
dc.date.issued	2019	ru_RU
dc.identifier.citation	Nigmatullin, R.R.Process of electrochemical electrode modification by polyaniline in the frame of percolation model/ Nigmatullin, R.R.Budnikov, H.C., Mustafin, A.G., Sidelnikov, A.V., Andriianova, A.N., Shigapova, A.R.//Journal of Solid State Electrochemistry (2019) 23:1221–1235	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=199251	ru_RU
dc.description.abstract	J SOLID STATE ELECTR	ru_RU
dc.description.abstract	The polymer has wide application as chemical modifier of electrodes for voltammetry. Electrochemical polymerization of aniline includes in itself some oxidation/reduction stages of electroactive groups. In the result of this process, polyaniline structures of different contents are formed. The qualitative and quantitative contents of polymer film and its area and morphology during the polymerization process play an important role in electroconductivity and response of the final synthesis product on analyte.We demonstrate a possibility of quantitative description of the polyaniline electrochemical polymerization process in the frame of percolation model covering wide temporal range (100–500 reduction/oxidation cycles). We can evaluate the basic parameters (number of percolation channels and fractal dimensions with respect to the applied potential) characterizing the quality of electrode polymer cover. The microphotos obtained with the help of the high-resolution scanning electron microscope support the obtained results independently.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	polyaniline	ru_RU
dc.subject	percolation model	ru_RU
dc.subject	voltammogram	ru_RU
dc.subject	fractal dimension	ru_RU
dc.title	Process of electrochemical electrode modification by polyaniline in the frame of percolation model	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU