КФУ. Карточка публикации. Thermally induced cyclization of L‐isoleucyl‐L‐alanine in solid state: Effect of dipeptide structure on reaction temperature and self‐assembly

RUS

- EN
- 中文
- ES

THERMALLY INDUCED CYCLIZATION OF L‐ISOLEUCYL‐L‐ALANINE IN SOLID STATE: EFFECT OF DIPEPTIDE STRUCTURE ON REACTION TEMPERATURE AND SELF‐ASSEMBLY

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2019

Язык

английский

Авторы, сотрудники КФУ

Герасимов Александр Владимирович, автор

Горбачук Валерий Виленович, автор

Зиганшин Марат Ахмедович, автор

Ларионов Радик Анатольевич, автор

Мухаметзянов Тимур Анварович, автор

Хаяров Хасан Рафаэлевич, автор

Библиографическое описание на языке оригинала

Ziganshin, M.A., Larionov, R.A., Gerasimov, A.V., Ziganshina, S.A., Klimovitskii, A.E., Khayarov, Kh.R., Mukhametzyanov T.A., Gorbatchuk, V.V. Thermally induced cyclization of L‐isoleucyl‐L‐alanine in solid state: Effect of dipeptide structure on reaction temperature and self‐assembly // Journal of Peptide Science. - 2019. - Vol.25, Is.8. - Art. № e3177.

Аннотация

Thermal treatment of short‐chain oligopeptides is able to initiate the process oftheir self‐assembly with the formation of organic nanostructures with uniqueproperties. On the other hand, heating can lead to a chemical reaction with theformation of new substances with specific properties and ability to form structureswith different morphology. Therefore, in order to have a desired process, researcherneeds to find its temperature range. In the present work, cyclization ofL‐isoleucyl‐L‐alanine dipeptide in the solid state upon heating was studied. Kinetic parameters ofthis reaction were estimated within the approaches of the nonisothermal kinetics.The correlation between side chain structure of dipeptides and temperature of theircyclization in the solid state was found for the first time. This correlation may beused to predict the temperature, at which dipeptide self‐assembly changes to chem-ical reaction.

Ключевые слова

cyclization of dipeptide, self‐assembly of dipeptide, solid‐state reaction, kinetic analysis, organicnanostructures, structure‐property correlation, NMR

Название журнала

Journal of Peptide Science

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85069517007&doi=10.1002%2fpsc.3177&partnerID=40&md5=7b29e39cf72f4f146594ab2e6fcad156

Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку

https://repository.kpfu.ru/?p_id=206707

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Герасимов Александр Владимирович	ru_RU
dc.contributor.author	Горбачук Валерий Виленович	ru_RU
dc.contributor.author	Зиганшин Марат Ахмедович	ru_RU
dc.contributor.author	Ларионов Радик Анатольевич	ru_RU
dc.contributor.author	Мухаметзянов Тимур Анварович	ru_RU
dc.contributor.author	Хаяров Хасан Рафаэлевич	ru_RU
dc.date.accessioned	2019-01-01T00:00:00Z	ru_RU
dc.date.available	2019-01-01T00:00:00Z	ru_RU
dc.date.issued	2019	ru_RU
dc.identifier.citation	Ziganshin, M.A., Larionov, R.A., Gerasimov, A.V., Ziganshina, S.A., Klimovitskii, A.E., Khayarov, Kh.R., Mukhametzyanov T.A., Gorbatchuk, V.V. Thermally induced cyclization of L‐isoleucyl‐L‐alanine in solid state: Effect of dipeptide structure on reaction temperature and self‐assembly // Journal of Peptide Science. - 2019. - Vol.25, Is.8. - Art. № e3177.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=206707	ru_RU
dc.description.abstract	Journal of Peptide Science	ru_RU
dc.description.abstract	Thermal treatment of short‐chain oligopeptides is able to initiate the process oftheir self‐assembly with the formation of organic nanostructures with uniqueproperties. On the other hand, heating can lead to a chemical reaction with theformation of new substances with specific properties and ability to form structureswith different morphology. Therefore, in order to have a desired process, researcherneeds to find its temperature range. In the present work, cyclization ofL‐isoleucyl‐L‐alanine dipeptide in the solid state upon heating was studied. Kinetic parameters ofthis reaction were estimated within the approaches of the nonisothermal kinetics.The correlation between side chain structure of dipeptides and temperature of theircyclization in the solid state was found for the first time. This correlation may beused to predict the temperature, at which dipeptide self‐assembly changes to chem-ical reaction.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	cyclization of dipeptide	ru_RU
dc.subject	self‐assembly of dipeptide	ru_RU
dc.subject	solid‐state reaction	ru_RU
dc.subject	kinetic analysis	ru_RU
dc.subject	organicnanostructures	ru_RU
dc.subject	structure‐property correlation	ru_RU
dc.subject	NMR	ru_RU
dc.title	Thermally induced cyclization of L‐isoleucyl‐L‐alanine in solid state: Effect of dipeptide structure on reaction temperature and self‐assembly	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU