КФУ. Карточка публикации. Novel cu(ii), ni(ii), zn(ii), cd(ii), and mg(ii) complexes with a series of 2-arylhydrazono-1,3-dicarbonyl compounds. synthesis, structure and spectroscopic characteristics

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NOVEL CU(II), NI(II), ZN(II), CD(II), AND MG(II) COMPLEXES WITH A SERIES OF 2-ARYLHYDRAZONO-1,3-DICARBONYL COMPOUNDS. SYNTHESIS, STRUCTURE AND SPECTROSCOPIC CHARACTERISTICS

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2020

Язык

русский

Авторы, сотрудники КФУ

Базан Лия Вячеславовна, автор

Другие авторы

Воронкова Виолета Константиновна, автор

Библиографическое описание на языке оригинала

Kovalchukova O.V. Novel cu(ii), ni(ii), zn(ii), cd(ii), and mg(ii) complexes with a series of 2-arylhydrazono-1,3-dicarbonyl compounds. synthesis, structure and spectroscopic characteristics / Olga V.Kovalchukova, Vu Thi Ngoc Anh, Andrey N.Utenyshev, Adam I.Stash, Mikhail A.Ryabov, Al Tahan Rana Abdulila Abbas, Violetta K.Voronkova, Leah V.Bazan // Polyhedron (Available online 8 April 2020, 114557) https://doi.org/10.1016/j.poly.2020.114557

Аннотация

A series of novel metal complexes of Cu(II), Ni(II), Zn(II), Cd(II), and Mg(II) with four N-heterocyclic derivatives of 2-arylhydrazono-1,3-dicarbonyl compounds were isolated and identified by FT IR, 1H NMR, EPR, and UV–Vis spectroscopy. The crystallographic data for two organic ligands as well as Mg(II) and Ni(II) complexes were obtained. It was indicated that the organic species exist in the form of hydrazo-tautomers. The Ni complex is monomeric and is characterized by the tridentate coordination of the ligand through a deprotonated N-atom of the hydrazo-fragment and two neighboring O-atoms of the carbonyl and deprotonated hydroxy-groups. In the case of the Mg complex the polymeric structure is observed with the additional coordination through the sulfamide group of the organic specie. Formation constants of the complexes in ethanol aqueous solutions were calculated and correlated with some physical characteristics of the metal cations. Structures of yet unstudied metal complexes were proposed based on quantum-chemical modeling at the DFT/B3LYP level.

Ключевые слова

EPR, 2-arylhydrazono-1,3-dicarbonyl compounds, metal complexes, X-ray structural analysis, spectroscopic characteristics, quantum chemistry

Название журнала

POLYHEDRON

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https://repository.kpfu.ru/?p_id=228524

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Базан Лия Вячеславовна	ru_RU
dc.contributor.author	Воронкова Виолета Константиновна	ru_RU
dc.date.accessioned	2020-01-01T00:00:00Z	ru_RU
dc.date.available	2020-01-01T00:00:00Z	ru_RU
dc.date.issued	2020	ru_RU
dc.identifier.citation	Kovalchukova O.V. Novel cu(ii), ni(ii), zn(ii), cd(ii), and mg(ii) complexes with a series of 2-arylhydrazono-1,3-dicarbonyl compounds. synthesis, structure and spectroscopic characteristics / Olga V.Kovalchukova, Vu Thi Ngoc Anh, Andrey N.Utenyshev, Adam I.Stash, Mikhail A.Ryabov, Al Tahan Rana Abdulila Abbas, Violetta K.Voronkova, Leah V.Bazan // Polyhedron (Available online 8 April 2020, 114557) https://doi.org/10.1016/j.poly.2020.114557	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=228524	ru_RU
dc.description.abstract	POLYHEDRON	ru_RU
dc.description.abstract	A series of novel metal complexes of Cu(II), Ni(II), Zn(II), Cd(II), and Mg(II) with four N-heterocyclic derivatives of 2-arylhydrazono-1,3-dicarbonyl compounds were isolated and identified by FT IR, 1H NMR, EPR, and UV–Vis spectroscopy. The crystallographic data for two organic ligands as well as Mg(II) and Ni(II) complexes were obtained. It was indicated that the organic species exist in the form of hydrazo-tautomers. The Ni complex is monomeric and is characterized by the tridentate coordination of the ligand through a deprotonated N-atom of the hydrazo-fragment and two neighboring O-atoms of the carbonyl and deprotonated hydroxy-groups. In the case of the Mg complex the polymeric structure is observed with the additional coordination through the sulfamide group of the organic specie. Formation constants of the complexes in ethanol aqueous solutions were calculated and correlated with some physical characteristics of the metal cations. Structures of yet unstudied metal complexes were proposed based on quantum-chemical modeling at the DFT/B3LYP level.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	EPR	ru_RU
dc.subject	2-arylhydrazono-1	ru_RU
dc.subject	3-dicarbonyl compounds	ru_RU
dc.subject	metal complexes	ru_RU
dc.subject	X-ray structural analysis	ru_RU
dc.subject	spectroscopic characteristics	ru_RU
dc.subject	quantum chemistry	ru_RU
dc.title	Novel cu(ii), ni(ii), zn(ii), cd(ii), and mg(ii) complexes with a series of 2-arylhydrazono-1,3-dicarbonyl compounds. synthesis, structure and spectroscopic characteristics	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU