| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2019 |
| Язык | английский |
|
Джамбастиани Джулиано , автор
Хуснуриялова Алия Фанусовна, автор
Яхваров Дмитрий Григорьевич, автор
|
| Библиографическое описание на языке оригинала |
Luconi L., Tuci G., Yakhvarov D., Poli G., Rossin A., Khusnuriyalova A., Giambastiani G. Imidazole-bridged tetrameric group(IV) heteroleptic complexes from the spontaneous metal-ligand assembly of a potentially N4-tetradentate ligand. Eur. J. Inorg. Chem. 2019, 39-40, 4384-4393. |
| Аннотация |
The imidazole-containing N4-tetradentate ligand N-(2-(1H-imidazol-2-yl)-3-(pyridin-2-yl)propyl)-2,6-diisopropylaniline (L2H) and its N-benzyl-protected variant (L2Bn) at the
imidazole fragment have been synthesized and fully characterized. Both molecules
contain an unresolved Csp3 stereogenic center. The coordination behavior of the
newly prepared ligands towards Group IV metal ions (MIV = Zr, Hf) has been examined
through multinuclear 1H and 13C{1H} NMR spectroscopy and selected single crystal
X-ray structural analyses. The ability of the imidazole fragment to enter the metal
coordination sphere as a neutral or a monoanionic system has been also investigated,
unveiling quite original coordination modes as well as unexpected molecular
architectures. |
| Ключевые слова |
Hafnium, Ligand design, N ligands, Self-assembly, Zirconium |
| Название журнала |
Eur.J. Inorg.Chem.
|
| URL |
https://www.scopus.com/record/display.uri?eid=2-s2.0-85072230323&origin=resultslist&sort=plf-f&src=s&st1=Khusnuriyalova&st2=&sid=12b21140add0da846074e343aa1f093b&sot=b&sdt=b&sl=27&s=AUTHOR-NAME%28Khusnuriyalova%29&relpos=1&citeCnt=0&searchTerm= |
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=235397 |
| Файлы ресурса | |
|
|
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Джамбастиани Джулиано |
ru_RU |
| dc.contributor.author |
Хуснуриялова Алия Фанусовна |
ru_RU |
| dc.contributor.author |
Яхваров Дмитрий Григорьевич |
ru_RU |
| dc.date.accessioned |
2019-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2019-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2019 |
ru_RU |
| dc.identifier.citation |
Luconi L., Tuci G., Yakhvarov D., Poli G., Rossin A., Khusnuriyalova A., Giambastiani G. Imidazole-bridged tetrameric group(IV) heteroleptic complexes from the spontaneous metal-ligand assembly of a potentially N4-tetradentate ligand. Eur. J. Inorg. Chem. 2019, 39-40, 4384-4393. |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=235397 |
ru_RU |
| dc.description.abstract |
Eur.J. Inorg.Chem. |
ru_RU |
| dc.description.abstract |
The imidazole-containing N4-tetradentate ligand N-(2-(1H-imidazol-2-yl)-3-(pyridin-2-yl)propyl)-2,6-diisopropylaniline (L2H) and its N-benzyl-protected variant (L2Bn) at the
imidazole fragment have been synthesized and fully characterized. Both molecules
contain an unresolved Csp3 stereogenic center. The coordination behavior of the
newly prepared ligands towards Group IV metal ions (MIV = Zr, Hf) has been examined
through multinuclear 1H and 13C{1H} NMR spectroscopy and selected single crystal
X-ray structural analyses. The ability of the imidazole fragment to enter the metal
coordination sphere as a neutral or a monoanionic system has been also investigated,
unveiling quite original coordination modes as well as unexpected molecular
architectures. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
Hafnium |
ru_RU |
| dc.subject |
Ligand design |
ru_RU |
| dc.subject |
N ligands |
ru_RU |
| dc.subject |
Self-assembly |
ru_RU |
| dc.subject |
Zirconium |
ru_RU |
| dc.title |
Imidazole-bridged tetrameric group(IV) heteroleptic complexes from the spontaneous metal-ligand assembly of a potentially N4-tetradentate ligand |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
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