| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2017 |
| Язык | английский |
|
Ермакова Алина Марселовна, автор
Коновалов Александр Иванович, автор
Морозова Юлия Эрнестовна, автор
Шалаева Яна Викторовна, автор
|
|
Кадиров Марсил Кахирович, автор
Казакова Элла Хатибовна, автор
Низамеев Ирек Рашатович, автор
Сякаев Виктор Васильевич, автор
|
| Библиографическое описание на языке оригинала |
Ya. V. Shalaeva, Novel thermoresponsive water-soluble oligomers based on amphiphilic calixresorcinarenes / Ya. V. Shalaeva, Ju. E. Morozova, V. V. Syakaev, E. Kh. Kazakova, A. M. Ermakova, I. R. Nizameev, M. K. Kadirov, A. I. Konovalov. // Supramol. Chem. - 2017. - V 29. - N 8. - P. 575–584. DOI: 10.1080/10610278.2017.1298765 |
| Аннотация |
Novel water-soluble thermoresponsive oligomers TO1 and TO2 were obtained by reaction of amidoamine tetramethylcalixresorcinarenes (C1) and tetrapentylcalixresorcinarenes (C5) with ethylene glycol diglycidyl ether. The compounds were characterised by 1 H and FT-PGSE NMR, FTIR, static light scattering and elemental analysis. The thermoresponsive properties of oligomers were
investigated by spectrophotometry, DLS, FT-PGSE NMR and TEM. The cloud points of oligomers (43 ?C for TO1 (5 mg/ml) and 41 ?C for TO2 (1.2 mg/ml), respectively) were determined. The influence of salts effect on TO2 cloud points was investigated. The binding of anti-inflammatory drug naproxen (Nap) at 20 ?C by TO1 and TO2 and its partial release at cloud points of oligomers in aqueous solution are observed using fluorescence and FT-PGSE NMR methods. New example of
creating of thermoresponsive macrocyclic systems on the basis of amidoamine calixresorcinarenes with possibility of substrate binding and release under the influence of termo-stimuli in an aqueous solution was shown. |
| Ключевые слова |
calixresorcinarenes, thermoresponsive oligomers, fluorescence, naproxen |
| Название журнала |
Supramolecular Chemistry
|
| URL |
https://www.tandfonline.com/doi/full/10.1080/10610278.2017.1298765 |
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=241470 |
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Ермакова Алина Марселовна |
ru_RU |
| dc.contributor.author |
Коновалов Александр Иванович |
ru_RU |
| dc.contributor.author |
Морозова Юлия Эрнестовна |
ru_RU |
| dc.contributor.author |
Шалаева Яна Викторовна |
ru_RU |
| dc.contributor.author |
Кадиров Марсил Кахирович |
ru_RU |
| dc.contributor.author |
Казакова Элла Хатибовна |
ru_RU |
| dc.contributor.author |
Низамеев Ирек Рашатович |
ru_RU |
| dc.contributor.author |
Сякаев Виктор Васильевич |
ru_RU |
| dc.date.accessioned |
2017-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2017-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2017 |
ru_RU |
| dc.identifier.citation |
Ya. V. Shalaeva, Novel thermoresponsive water-soluble oligomers based on amphiphilic calixresorcinarenes / Ya. V. Shalaeva, Ju. E. Morozova, V. V. Syakaev, E. Kh. Kazakova, A. M. Ermakova, I. R. Nizameev, M. K. Kadirov, A. I. Konovalov. // Supramol. Chem. - 2017. - V 29. - N 8. - P. 575–584. DOI: 10.1080/10610278.2017.1298765 |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=241470 |
ru_RU |
| dc.description.abstract |
Supramolecular Chemistry |
ru_RU |
| dc.description.abstract |
Novel water-soluble thermoresponsive oligomers TO1 and TO2 were obtained by reaction of amidoamine tetramethylcalixresorcinarenes (C1) and tetrapentylcalixresorcinarenes (C5) with ethylene glycol diglycidyl ether. The compounds were characterised by 1 H and FT-PGSE NMR, FTIR, static light scattering and elemental analysis. The thermoresponsive properties of oligomers were
investigated by spectrophotometry, DLS, FT-PGSE NMR and TEM. The cloud points of oligomers (43 ?C for TO1 (5 mg/ml) and 41 ?C for TO2 (1.2 mg/ml), respectively) were determined. The influence of salts effect on TO2 cloud points was investigated. The binding of anti-inflammatory drug naproxen (Nap) at 20 ?C by TO1 and TO2 and its partial release at cloud points of oligomers in aqueous solution are observed using fluorescence and FT-PGSE NMR methods. New example of
creating of thermoresponsive macrocyclic systems on the basis of amidoamine calixresorcinarenes with possibility of substrate binding and release under the influence of termo-stimuli in an aqueous solution was shown. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
calixresorcinarenes |
ru_RU |
| dc.subject |
thermoresponsive oligomers |
ru_RU |
| dc.subject |
fluorescence |
ru_RU |
| dc.subject |
naproxen |
ru_RU |
| dc.title |
Novel thermoresponsive water-soluble oligomers based on amphiphilic calixresorcinarenes |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
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