| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2017 |
| Язык | английский |
|
Антипин Игорь Сергеевич, автор
Ермакова Алина Марселовна, автор
Коновалов Александр Иванович, автор
Морозова Юлия Эрнестовна, автор
Шалаева Яна Викторовна, автор
|
|
Кадиров Марсил Кахирович, автор
Низамеев Ирек Рашатович, автор
Сякаев Виктор Васильевич, автор
|
| Библиографическое описание на языке оригинала |
Alina M. Ermakova, The supramolecular approach to the phase transfer of carboxylic calixresorcinarene-capped silver nanoparticles. / Alina M. Ermakova, Julia E. Morozova Yana V. Shalaeva, Victor V. Syakaev, Irek R. Nizameev, Marsil K. Kadirov, Igor S. Antipin, Alexander I. Konovalov // Colloids and Surfaces A. – 2017. – V. 524. – P.127–134. DOI: 10.1016/j.colsurfa.2017.04.045 |
| Аннотация |
The octacarboxylic derivative of tetrapentylcalix[4]resorcinarene (1) was used as stabilizer for preparation of silver nanoparticles (AgNPs) hydrosol. The calixresorcinarene-capped nanoparticles Ag@1 are stably dispersed in an aqueous colloid solution and have an average diameter of 4–6 nm (TEM). The interaction of the macrocycle 1, possessed the receptor properties, with the cationic surfactant cetyltrimetylammonium bromide (CTAB) leads to the hydrophobization of AgNPs hydrosol. It was shown, that macrocycle 1 in its individual solution forms the hydrophobic associate with 8 mol of CTAB (1H NMR, 2D NOESY). Various and complicated influence of CTAB/macrocycle molar ratio on the hydrophobization of AgNPs and their transfer into organic phase was demonstrated. The initial Ag@1 and modified Ag@1-CTAB were characterized by UV-vis and FTIR spectroscopy, DLS, and TG/DSC methods It was shown that the efficiency of water/organic phase transfer depends on the macrocycle/surfactant molar ratio. The presented supramolecular approach can be useful to form the ordered
nanostructures through supramolecular modification and self-organization of hybrid metal nanoparticles |
| Ключевые слова |
Silver nanoparticles, Calix[4]resorcinarene, Phase transfer, Ionic associate |
| Название журнала |
Colloids and Surfaces A: Physicochemical and Engineering Aspects
|
| URL |
https://www.sciencedirect.com/science/article/pii/S0927775717303771?via%3Dihub |
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=241473 |
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Антипин Игорь Сергеевич |
ru_RU |
| dc.contributor.author |
Ермакова Алина Марселовна |
ru_RU |
| dc.contributor.author |
Коновалов Александр Иванович |
ru_RU |
| dc.contributor.author |
Морозова Юлия Эрнестовна |
ru_RU |
| dc.contributor.author |
Шалаева Яна Викторовна |
ru_RU |
| dc.contributor.author |
Кадиров Марсил Кахирович |
ru_RU |
| dc.contributor.author |
Низамеев Ирек Рашатович |
ru_RU |
| dc.contributor.author |
Сякаев Виктор Васильевич |
ru_RU |
| dc.date.accessioned |
2017-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2017-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2017 |
ru_RU |
| dc.identifier.citation |
Alina M. Ermakova, The supramolecular approach to the phase transfer of carboxylic calixresorcinarene-capped silver nanoparticles. / Alina M. Ermakova, Julia E. Morozova Yana V. Shalaeva, Victor V. Syakaev, Irek R. Nizameev, Marsil K. Kadirov, Igor S. Antipin, Alexander I. Konovalov // Colloids and Surfaces A. – 2017. – V. 524. – P.127–134. DOI: 10.1016/j.colsurfa.2017.04.045 |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=241473 |
ru_RU |
| dc.description.abstract |
Colloids and Surfaces A: Physicochemical and Engineering Aspects |
ru_RU |
| dc.description.abstract |
The octacarboxylic derivative of tetrapentylcalix[4]resorcinarene (1) was used as stabilizer for preparation of silver nanoparticles (AgNPs) hydrosol. The calixresorcinarene-capped nanoparticles Ag@1 are stably dispersed in an aqueous colloid solution and have an average diameter of 4–6 nm (TEM). The interaction of the macrocycle 1, possessed the receptor properties, with the cationic surfactant cetyltrimetylammonium bromide (CTAB) leads to the hydrophobization of AgNPs hydrosol. It was shown, that macrocycle 1 in its individual solution forms the hydrophobic associate with 8 mol of CTAB (1H NMR, 2D NOESY). Various and complicated influence of CTAB/macrocycle molar ratio on the hydrophobization of AgNPs and their transfer into organic phase was demonstrated. The initial Ag@1 and modified Ag@1-CTAB were characterized by UV-vis and FTIR spectroscopy, DLS, and TG/DSC methods It was shown that the efficiency of water/organic phase transfer depends on the macrocycle/surfactant molar ratio. The presented supramolecular approach can be useful to form the ordered
nanostructures through supramolecular modification and self-organization of hybrid metal nanoparticles |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
Silver nanoparticles |
ru_RU |
| dc.subject |
Calix[4]resorcinarene |
ru_RU |
| dc.subject |
Phase transfer |
ru_RU |
| dc.subject |
Ionic associate |
ru_RU |
| dc.title |
The supramolecular approach to the phase transfer of carboxylic calixresorcinarene-capped silver nanoparticles |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
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