КФУ. Карточка публикации. Nanoassociates of amphiphiliccarboxy-calixresorcinarene and cetylpyridinuim chloride: the search of optimal macrocycle/surfactant molar ratio

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NANOASSOCIATES OF AMPHIPHILICCARBOXY-CALIXRESORCINARENE AND CETYLPYRIDINUIM CHLORIDE: THE SEARCH OF OPTIMAL MACROCYCLE/SURFACTANT MOLAR RATIO

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2018

Язык

английский

Авторы, сотрудники КФУ

Ермакова Алина Марселовна, автор

Коновалов Александр Иванович, автор

Морозова Юлия Эрнестовна, автор

Шалаева Яна Викторовна, автор

Другие авторы

Кадиров Марсил Кахирович, автор

Низамеев Ирек Рашатович, автор

Сякаев Виктор Васильевич, автор

Библиографическое описание на языке оригинала

Morozova J. E., Nanoassociates of amphiphiliccarboxy-calixresorcinarene and cetylpyridinuim chloride: the search of optimal macrocycle/surfactant molar ratio. / Morozova J. E., Syakaev V. V., Shalaeva Y. V., Ermakova A. M., Nizameev I. R., Kadirov M. K., Konovalov A. I. // Colloids Surf., A. – 2018. – V. 553. – P. 569-577. DOI: 10.1016/j.colsurfa.2018.05.077

Аннотация

Here we present the supramolecular surfactant-macrocycle system which properties are independent on system composition in the wide range of components concentrations. The study of the interaction of octacarboxy-tetra(p-phenylene-oxy-pentyl)calixresorcinarene (C5R) and cetylpyridinuim chloride (CPC) in mixed aqueous solutions were performed by dynamic light scattering and electrophoretic methods, 1H and FT-PGSE NMR methods, absorption and ﬂuorescence spectroscopy, and TEM. The variation of CPC/C5R molar ratio from 30/1 to 10/1 leads to the formation of nanoassociates with similar composition, size, surface potential value, and improved (in compare with CPC) solubilizing properties. The preparation of mixed supramolecular systems which properties are independent on system composition in the wide range of components concentrations is an elegant example of the producing of colloidal materials with the required morphology and properties.

Ключевые слова

Calix[4]resorcinarene, Cetylpyridinuim chloride, Supramolecular system, FT-PGSE NMR, Solubilization

Название журнала

Colloids and Surfaces A: Physicochemical and Engineering Aspects

URL

https://www.sciencedirect.com/science/article/pii/S0927775718304539?via%3Dihub

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https://repository.kpfu.ru/?p_id=241478

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Ермакова Алина Марселовна	ru_RU
dc.contributor.author	Коновалов Александр Иванович	ru_RU
dc.contributor.author	Морозова Юлия Эрнестовна	ru_RU
dc.contributor.author	Шалаева Яна Викторовна	ru_RU
dc.contributor.author	Кадиров Марсил Кахирович	ru_RU
dc.contributor.author	Низамеев Ирек Рашатович	ru_RU
dc.contributor.author	Сякаев Виктор Васильевич	ru_RU
dc.date.accessioned	2018-01-01T00:00:00Z	ru_RU
dc.date.available	2018-01-01T00:00:00Z	ru_RU
dc.date.issued	2018	ru_RU
dc.identifier.citation	Morozova J. E., Nanoassociates of amphiphiliccarboxy-calixresorcinarene and cetylpyridinuim chloride: the search of optimal macrocycle/surfactant molar ratio. / Morozova J. E., Syakaev V. V., Shalaeva Y. V., Ermakova A. M., Nizameev I. R., Kadirov M. K., Konovalov A. I. // Colloids Surf., A. – 2018. – V. 553. – P. 569-577. DOI: 10.1016/j.colsurfa.2018.05.077	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=241478	ru_RU
dc.description.abstract	Colloids and Surfaces A: Physicochemical and Engineering Aspects	ru_RU
dc.description.abstract	Here we present the supramolecular surfactant-macrocycle system which properties are independent on system composition in the wide range of components concentrations. The study of the interaction of octacarboxy-tetra(p-phenylene-oxy-pentyl)calixresorcinarene (C5R) and cetylpyridinuim chloride (CPC) in mixed aqueous solutions were performed by dynamic light scattering and electrophoretic methods, 1H and FT-PGSE NMR methods, absorption and ﬂuorescence spectroscopy, and TEM. The variation of CPC/C5R molar ratio from 30/1 to 10/1 leads to the formation of nanoassociates with similar composition, size, surface potential value, and improved (in compare with CPC) solubilizing properties. The preparation of mixed supramolecular systems which properties are independent on system composition in the wide range of components concentrations is an elegant example of the producing of colloidal materials with the required morphology and properties.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Calix[4]resorcinarene	ru_RU
dc.subject	Cetylpyridinuim chloride	ru_RU
dc.subject	Supramolecular system	ru_RU
dc.subject	FT-PGSE NMR	ru_RU
dc.subject	Solubilization	ru_RU
dc.title	Nanoassociates of amphiphiliccarboxy-calixresorcinarene and cetylpyridinuim chloride: the search of optimal macrocycle/surfactant molar ratio	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU