| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2018 |
| Язык | английский |
|
Ермакова Алина Марселовна, автор
Коновалов Александр Иванович, автор
Морозова Юлия Эрнестовна, автор
Шалаева Яна Викторовна, автор
|
|
Кадиров Марсил Кахирович, автор
Казакова Элла Хатибовна, автор
Низамеев Ирек Рашатович, автор
Сякаев Виктор Васильевич, автор
|
| Библиографическое описание на языке оригинала |
Morozova Ju. E., The supramolecular polymer complexes with oppositely charged calixresorcinarene: hydrophobic domain formation and synergistic binding modes. / Morozova Ju. E., Syakaev V. V., Shalaeva Ya. V., Ermakova A. M., Nizameev I. R., Kadirov M. K., Kazakova E. Kh., Konovalov A. I. // Soft Matter. - 2018. – V.14. – P.1799-1810. DOI: 10.1039/c8sm00015h |
| Аннотация |
The association of branched polyethyleneimine (PEI) with a series of octacarboxy-calixresorcinarenes bearing different low-rim substituents leads to the formation of nanosized supramolecular complexes. The PEI–macrocycle complexes have fine-tunable sizes regulated by variations in the self-association capacity of the calixresorcinarenes. In the supramolecular complexes, hydrophobic fragments of the
polymer and calixresorcinarenes form cooperative hydrophobic domains which provide synergistic enhancement of guest molecule binding. The formation of the supramolecular complexes was investigated by NMR FT-PGSE, NMR 2D NOESY, DLS and TEM methods. In addition, fluorimetry and UV-vis methods were used with the help of optical probes, namely water-soluble Crystal Violet and water-insoluble Orange OT. The investigation demonstrates the first example of the formation of
cooperative hydrophobic domains in supramolecular polyelectrolyte–macrocycle complexes which enhance the binding of both water-soluble and water-insoluble organic compounds. The presented supramolecular systems have potential as sensory and drug delivery systems. |
| Ключевые слова |
calixresorcinarene, polymer complexes, branched polyethyleneimine, hydrophobic domain |
| Название журнала |
SOFT MATTER
|
| URL |
https://pubs.rsc.org/en/content/articlelanding/2018/SM/c8sm00015h#!divAbstract |
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=241479 |
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Ермакова Алина Марселовна |
ru_RU |
| dc.contributor.author |
Коновалов Александр Иванович |
ru_RU |
| dc.contributor.author |
Морозова Юлия Эрнестовна |
ru_RU |
| dc.contributor.author |
Шалаева Яна Викторовна |
ru_RU |
| dc.contributor.author |
Кадиров Марсил Кахирович |
ru_RU |
| dc.contributor.author |
Казакова Элла Хатибовна |
ru_RU |
| dc.contributor.author |
Низамеев Ирек Рашатович |
ru_RU |
| dc.contributor.author |
Сякаев Виктор Васильевич |
ru_RU |
| dc.date.accessioned |
2018-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2018-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2018 |
ru_RU |
| dc.identifier.citation |
Morozova Ju. E., The supramolecular polymer complexes with oppositely charged calixresorcinarene: hydrophobic domain formation and synergistic binding modes. / Morozova Ju. E., Syakaev V. V., Shalaeva Ya. V., Ermakova A. M., Nizameev I. R., Kadirov M. K., Kazakova E. Kh., Konovalov A. I. // Soft Matter. - 2018. – V.14. – P.1799-1810. DOI: 10.1039/c8sm00015h |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=241479 |
ru_RU |
| dc.description.abstract |
SOFT MATTER |
ru_RU |
| dc.description.abstract |
The association of branched polyethyleneimine (PEI) with a series of octacarboxy-calixresorcinarenes bearing different low-rim substituents leads to the formation of nanosized supramolecular complexes. The PEI–macrocycle complexes have fine-tunable sizes regulated by variations in the self-association capacity of the calixresorcinarenes. In the supramolecular complexes, hydrophobic fragments of the
polymer and calixresorcinarenes form cooperative hydrophobic domains which provide synergistic enhancement of guest molecule binding. The formation of the supramolecular complexes was investigated by NMR FT-PGSE, NMR 2D NOESY, DLS and TEM methods. In addition, fluorimetry and UV-vis methods were used with the help of optical probes, namely water-soluble Crystal Violet and water-insoluble Orange OT. The investigation demonstrates the first example of the formation of
cooperative hydrophobic domains in supramolecular polyelectrolyte–macrocycle complexes which enhance the binding of both water-soluble and water-insoluble organic compounds. The presented supramolecular systems have potential as sensory and drug delivery systems. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
calixresorcinarene |
ru_RU |
| dc.subject |
polymer complexes |
ru_RU |
| dc.subject |
branched polyethyleneimine |
ru_RU |
| dc.subject |
hydrophobic domain |
ru_RU |
| dc.title |
The supramolecular polymer complexes with oppositely charged calixresorcinarene: hydrophobic domain formation and synergistic binding modes |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
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