| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2018 |
|
Аникин Олег Викторович, автор
Киселев Владимир Дмитриевич, автор
Колесникова Анастасия Олеговна, автор
Корнилов Дмитрий Анатольевич, автор
|
| Другие авторы |
Шулятьев Алексей Александрович, Коновалов Александр Иванович |
| Библиографическое описание на языке оригинала |
Kiselev V.D., Kornilov D.A., Anikin O.V., Shulyatiev A.A., Kolesnikova A.O., Konovalov A.I. / Kinetics of the ene reactions of 4-phenyl-1,2,4-triazoline-3,5-dione with β-pinene and 2-carene: Temperature, high pressure, and solvent effects // International Journal of Chemical Kinetics. ─ 2018. ─ V.50. ─ P.651-658. |
| Аннотация |
The data on temperature, solvent, and high hydrostatic pressure influence on the rate
of the ene reactions of 4-phenyl-1,2,4-triazoline-3,5-dione (1) with 2-carene (2), and
𝛽-pinene (4) have been obtained. Ene reactions 1+2 and 1+4 have high heat effects:
ΔHr-n (1+2) −158.4, ΔHr-n(1+4) −159.2 kJ mol−1, 25 ◦ C, 1,2-dichloroethane.
The comparison of the activation volume (ΔV≠(1+2) −29.9 cm3 mol−1, toluene;
ΔV≠(1+4) −36.0 cm3 mol−1, ethyl acetate) and reaction volume values (ΔVr-n(1+2)
−24.0 cm3 mol−1, toluene; ΔVr-n(1+4) −30.4 cm3 mol−1, ethyl acetate) reveals more
compact cyclic transition states in comparison with the acyclic reaction products 3
and 5. In the series of nine solvents, the reaction rate of 1+2 increases 260-fold and
1+4 increases 200-fold, respectively, but not due to the solvent polarity. |
| Ключевые слова |
Activation volume, high pressure, kinetics, reaction heat, reaction volume |
| Название журнала |
International Journal of Chemical Kinetics
|
| Издательство |
Wiley |
| URL |
https://doi.org/10.1002/kin.21189 |
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=249637 |
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Аникин Олег Викторович |
ru_RU |
| dc.contributor.author |
Киселев Владимир Дмитриевич |
ru_RU |
| dc.contributor.author |
Колесникова Анастасия Олеговна |
ru_RU |
| dc.contributor.author |
Корнилов Дмитрий Анатольевич |
ru_RU |
| dc.date.accessioned |
2018-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2018-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2018 |
ru_RU |
| dc.identifier.citation |
Kiselev V.D., Kornilov D.A., Anikin O.V., Shulyatiev A.A., Kolesnikova A.O., Konovalov A.I. / Kinetics of the ene reactions of 4-phenyl-1,2,4-triazoline-3,5-dione with β-pinene and 2-carene: Temperature, high pressure, and solvent effects // International Journal of Chemical Kinetics. ─ 2018. ─ V.50. ─ P.651-658. |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=249637 |
ru_RU |
| dc.description.abstract |
International Journal of Chemical Kinetics |
ru_RU |
| dc.description.abstract |
The data on temperature, solvent, and high hydrostatic pressure influence on the rate
of the ene reactions of 4-phenyl-1,2,4-triazoline-3,5-dione (1) with 2-carene (2), and
𝛽-pinene (4) have been obtained. Ene reactions 1+2 and 1+4 have high heat effects:
ΔHr-n (1+2) −158.4, ΔHr-n(1+4) −159.2 kJ mol−1, 25 ◦ C, 1,2-dichloroethane.
The comparison of the activation volume (ΔV≠(1+2) −29.9 cm3 mol−1, toluene;
ΔV≠(1+4) −36.0 cm3 mol−1, ethyl acetate) and reaction volume values (ΔVr-n(1+2)
−24.0 cm3 mol−1, toluene; ΔVr-n(1+4) −30.4 cm3 mol−1, ethyl acetate) reveals more
compact cyclic transition states in comparison with the acyclic reaction products 3
and 5. In the series of nine solvents, the reaction rate of 1+2 increases 260-fold and
1+4 increases 200-fold, respectively, but not due to the solvent polarity. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.publisher |
Wiley |
ru_RU |
| dc.subject |
Activation volume |
ru_RU |
| dc.subject |
high pressure |
ru_RU |
| dc.subject |
kinetics |
ru_RU |
| dc.subject |
reaction heat |
ru_RU |
| dc.subject |
reaction volume |
ru_RU |
| dc.title |
Kinetics of the ene reactions of 4-phenyl-1,2,4-triazoline-3,5-dione with 𝜷-pinene and 2-carene: Temperature, high pressure, and solvent effects |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
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