| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2022 |
| Язык | английский |
|
Зиганшина Альбина Юлдузовна, автор
|
| Библиографическое описание на языке оригинала |
Kashapov, R. Effect of preorganization and amphiphilicity of calix[4]arene platform on functional properties of viologen derivatives / R. Kashapov, Y. Razuvayeva, A. Ziganshina, A. Sapunova, A. Lyubina, S. Amerhanova, N. Kulik, A. Voloshina, I. Nizameev, V. Salnikov, L. Zakharova // J. Mol. Liq. – 2022. – 345. – 117801. |
| Аннотация |
A series of novel amphiphilic cavitands of calix[4]resorcinols with viologen fragments on the upper rim synthesized through a combination of viologen moieties and amphiphilic macrocyclic skeleton is reported. The influence of their structure on self-assembly, solubilization and biological properties was found. The driving force of the self-assembly of the synthesized macrocycles is the hydrophobic interactions of their hydrocarbon chains through additional π-stacking interaction between the aromatic rings of neighboring macrocycle molecules, which is enhanced with an increase in the length of the alkyl chains on the lower rim. The lower hemotoxicity of long-chain viologen macrocycles, relative to viologen surfactant, the ability to bind therapeutic molecules and the selective cytotoxic activity to tumor cells are explicit references to viologen derivatives of calix[4]resorcinols as promising drug nanocontainers. |
| Ключевые слова |
calix[4]resorcines, viologens |
| Название журнала |
Journal of Molecular Liquids
|
| URL |
https://www.sciencedirect.com/science/article/abs/pii/S0167732221025265 |
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=262817 |
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Зиганшина Альбина Юлдузовна |
ru_RU |
| dc.date.accessioned |
2022-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2022-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2022 |
ru_RU |
| dc.identifier.citation |
Kashapov, R. Effect of preorganization and amphiphilicity of calix[4]arene platform on functional properties of viologen derivatives / R. Kashapov, Y. Razuvayeva, A. Ziganshina, A. Sapunova, A. Lyubina, S. Amerhanova, N. Kulik, A. Voloshina, I. Nizameev, V. Salnikov, L. Zakharova // J. Mol. Liq. – 2022. – 345. – 117801. |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=262817 |
ru_RU |
| dc.description.abstract |
Journal of Molecular Liquids |
ru_RU |
| dc.description.abstract |
A series of novel amphiphilic cavitands of calix[4]resorcinols with viologen fragments on the upper rim synthesized through a combination of viologen moieties and amphiphilic macrocyclic skeleton is reported. The influence of their structure on self-assembly, solubilization and biological properties was found. The driving force of the self-assembly of the synthesized macrocycles is the hydrophobic interactions of their hydrocarbon chains through additional π-stacking interaction between the aromatic rings of neighboring macrocycle molecules, which is enhanced with an increase in the length of the alkyl chains on the lower rim. The lower hemotoxicity of long-chain viologen macrocycles, relative to viologen surfactant, the ability to bind therapeutic molecules and the selective cytotoxic activity to tumor cells are explicit references to viologen derivatives of calix[4]resorcinols as promising drug nanocontainers. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
calix[4]resorcines |
ru_RU |
| dc.subject |
viologens |
ru_RU |
| dc.title |
Effect of preorganization and amphiphilicity of calix[4]arene platform on functional properties of viologen derivatives |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
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