| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2015 |
| Язык | английский |
|
Зиганшина Альбина Юлдузовна, автор
|
| Библиографическое описание на языке оригинала |
G. R. Nasretdinova, R. R. Fazleeva, R. K. Mukhitova, I. R. Nizameev, M. K. Kadirov, A. Yu. Ziganshina, V. V. Yanilkin / Electrochemical Mediated Synthesis of Silver Nanoparticles in Solution // Russ. J. Electrochem. – 2015. – 51. – 1029–1040. |
| Аннотация |
Methyl viologen MV2+ and tetraviologen calix[4]resorcinol MVCA-C
8+
5
with n-pentyl substituents in the resorcinol rings at potentials of MV2+/MV?+ and MVCA-C
8+
5
/MVCA-C
4?+
5
redox couples proved to be effective mediators of the electrochemical reduction of Ag+ ions in DMF/0.1 M Bu4NPF6. The potentiostatic nondiaphragm electrolysis at controlled mediator reduction potentials at room temperature using an Ag anode as an in situ supplier of Ag+ led to the formation of metallic silver nanoparticles in solution. The only resulting effect of electrolysis was the quantitative transfer of the metal anode into the metal nanoparticles in solution. In the case of MV2+, the nanoparticles aggregated into larger particles. MVCA-CC
8+
5
serves not only as a mediator, but also, to some extent, as a stabilizer of silver nanoparticles and can be recorded by a set of experimental methods. |
| Ключевые слова |
electrochemical synthesis, silver nanoparticles, mediator, methyl viologen, viologen calix[4]resorcinol |
| Название журнала |
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
|
| URL |
https://link.springer.com/article/10.1134/S1023193515110129#citeas |
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=262932 |
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Зиганшина Альбина Юлдузовна |
ru_RU |
| dc.date.accessioned |
2015-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2015-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2015 |
ru_RU |
| dc.identifier.citation |
G. R. Nasretdinova, R. R. Fazleeva, R. K. Mukhitova, I. R. Nizameev, M. K. Kadirov, A. Yu. Ziganshina, V. V. Yanilkin / Electrochemical Mediated Synthesis of Silver Nanoparticles in Solution // Russ. J. Electrochem. – 2015. – 51. – 1029–1040. |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=262932 |
ru_RU |
| dc.description.abstract |
RUSSIAN JOURNAL OF ELECTROCHEMISTRY |
ru_RU |
| dc.description.abstract |
Methyl viologen MV2+ and tetraviologen calix[4]resorcinol MVCA-C
8+
5
with n-pentyl substituents in the resorcinol rings at potentials of MV2+/MV?+ and MVCA-C
8+
5
/MVCA-C
4?+
5
redox couples proved to be effective mediators of the electrochemical reduction of Ag+ ions in DMF/0.1 M Bu4NPF6. The potentiostatic nondiaphragm electrolysis at controlled mediator reduction potentials at room temperature using an Ag anode as an in situ supplier of Ag+ led to the formation of metallic silver nanoparticles in solution. The only resulting effect of electrolysis was the quantitative transfer of the metal anode into the metal nanoparticles in solution. In the case of MV2+, the nanoparticles aggregated into larger particles. MVCA-CC
8+
5
serves not only as a mediator, but also, to some extent, as a stabilizer of silver nanoparticles and can be recorded by a set of experimental methods. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
electrochemical synthesis |
ru_RU |
| dc.subject |
silver nanoparticles |
ru_RU |
| dc.subject |
mediator |
ru_RU |
| dc.subject |
methyl viologen |
ru_RU |
| dc.subject |
viologen calix[4]resorcinol |
ru_RU |
| dc.title |
Electrochemical Mediated Synthesis of Silver Nanoparticles in Solution |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
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