Форма представления | Статьи в зарубежных журналах и сборниках |
Год публикации | 2014 |
Язык | английский |
|
Зиганшина Альбина Юлдузовна, автор
|
Библиографическое описание на языке оригинала |
V. V. Yanilkin, G. R. Nasybullina, E. D. Sultanova, A. Yu. Ziganshina, and A. I. Konovalov, Methyl viologen and tetraviologen calix[4]resorcinol as mediators of the electrochemical reduction of [PdCl4]2– with formation of finely dispersed Pd0 // Russ. Chem. Bull. – 2014. – 63. – 6. – 1409—1415. |
Аннотация |
Methyl viologen and tetraviologen calix[4]resorcinol with decyl substituents in the resorcinol cycles (MVCA-C10 8+) are mediators of the electrochemical reduction of complex dianion [PdCl4]2− facilitating its reduction on the glassy carbon electrode at 0.5–0.6 V. The reduction product of Pd2+ salt is finely dispersed metallic palladium, and its structure and some properties are determined by the mediator nature. When using methyl viologen, palladium is deposited on the electrode and dispersed as flakes in a solution, whereas in the case of MVCA-C10 8+ palladium is completely deposited on the electrode as nanoparticles together with calixresorcinol. |
Ключевые слова |
viologen calix[4]resorcinol, palladium tetrachloride, mediator, electrochemical reduction, palladium particles |
Название журнала |
Russian Chemical Bulletin
|
URL |
https://link.springer.com/article/10.1007/s11172-014-0611-x#citeas |
Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=262936 |
Полная запись метаданных ![](https://shelly.kpfu.ru/pdf/picture/arrow_black_right.gif) |
Поле DC |
Значение |
Язык |
dc.contributor.author |
Зиганшина Альбина Юлдузовна |
ru_RU |
dc.date.accessioned |
2014-01-01T00:00:00Z |
ru_RU |
dc.date.available |
2014-01-01T00:00:00Z |
ru_RU |
dc.date.issued |
2014 |
ru_RU |
dc.identifier.citation |
V. V. Yanilkin, G. R. Nasybullina, E. D. Sultanova, A. Yu. Ziganshina, and A. I. Konovalov, Methyl viologen and tetraviologen calix[4]resorcinol as mediators of the electrochemical reduction of [PdCl4]2– with formation of finely dispersed Pd0 // Russ. Chem. Bull. – 2014. – 63. – 6. – 1409—1415. |
ru_RU |
dc.identifier.uri |
https://repository.kpfu.ru/?p_id=262936 |
ru_RU |
dc.description.abstract |
Russian Chemical Bulletin |
ru_RU |
dc.description.abstract |
Methyl viologen and tetraviologen calix[4]resorcinol with decyl substituents in the resorcinol cycles (MVCA-C10 8+) are mediators of the electrochemical reduction of complex dianion [PdCl4]2− facilitating its reduction on the glassy carbon electrode at 0.5–0.6 V. The reduction product of Pd2+ salt is finely dispersed metallic palladium, and its structure and some properties are determined by the mediator nature. When using methyl viologen, palladium is deposited on the electrode and dispersed as flakes in a solution, whereas in the case of MVCA-C10 8+ palladium is completely deposited on the electrode as nanoparticles together with calixresorcinol. |
ru_RU |
dc.language.iso |
ru |
ru_RU |
dc.subject |
viologen calix[4]resorcinol |
ru_RU |
dc.subject |
palladium tetrachloride |
ru_RU |
dc.subject |
mediator |
ru_RU |
dc.subject |
electrochemical reduction |
ru_RU |
dc.subject |
palladium particles |
ru_RU |
dc.title |
Methyl viologen and tetraviologen calix[4]resorcinol as mediators of the electrochemical reduction of [PdCl4]2− with formation of finely dispersed Pd0 |
ru_RU |
dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|